Subscribe Now Subscribe Today
Science Alert
 
Blue
   
Curve Top
Journal of Applied Sciences
  Year: 2007 | Volume: 7 | Issue: 9 | Page No.: 1347-1350
DOI: 10.3923/jas.2007.1347.1350
 
Facebook Twitter Digg Reddit Linkedin StumbleUpon E-mail

Synthesis and Spectroscopic Studies of 2-Bromo N, N-Dimethylbenzylamine and Its Complexes with Mo(CO)6 and W(CO)6

Tariq Mahmud, Javed Iqbal, Muhammad Imran and Vickie Mckee

Abstract:
The new ligand, 2-bromo-N, N-Dimethylbenzylamine has been prepared according to scheme 1. The synthesized ligand was further reacted with Mo(CO)6 and W(CO)6 to yield 2-bromo N, N-Dimethylbenzylamine- Mo(CO)5 and 2-bromo N, N-Dimethylbenzylamine-W(CO)5 complexes, respectively. Both the ligand and its complexes were characterized on the basis of physical properties, elemental analysis data, infrared and nuclear magnetic resonance spectroscopy. It was found that the ligand has monodentate nature and coordinates with metal through its nitrogen atom thus replacing one CO molecule to maintain the charge density on metal centre.
PDF Fulltext XML References Citation Report Citation
How to cite this article:

Tariq Mahmud, Javed Iqbal, Muhammad Imran and Vickie Mckee, 2007. Synthesis and Spectroscopic Studies of 2-Bromo N, N-Dimethylbenzylamine and Its Complexes with Mo(CO)6 and W(CO)6. Journal of Applied Sciences, 7: 1347-1350.

DOI: 10.3923/jas.2007.1347.1350

URL: https://scialert.net/abstract/?doi=jas.2007.1347.1350

COMMENT ON THIS PAPER
 
 
 

 

 
 
 
 
 
 
 
 
 

 
 
 
 
 
 
 

Curve Bottom