Journal of Applied Sciences1812-56541812-5662Asian Network for Scientific Information10.3923/jas.2007.2011.2014BakarAnita Abu YunusRobiah ChuahA. Luqman Fakhru`l-RaziA. 122007715Some concerns have been raised regarding the oxidative stability of vegetable oil-base fluids. Thus, wide ranges of palm-based trimethylolpropane esters, which contain different percentages of partial esters, were synthesized. The palm-based TMP were esterified from Palm Oil Methyl Esters (POME) with trimethylolpropane [2-ethyl-2-(hydroxymethyl)-1,3-propanediol;TMP] and sodium methoxide (CH3ONa) as catalyst. Quantification of methyl esters, mono, di- and tri-TMP esters were performed using a gas chromatography (GC), with a high temperature capillary column (SGE HT5), operated at a temperature gradient of 6°C min-1 starting from 80 to 340°C. The influence of operating variables (temperature, pressure, molar ratio of palm methyl esters to TMP and catalyst amount) on diesters formation was studied and analyzed. Palm oil TMP ester containing 10-30% partial esters (monoesters and diesters) was successfully synthesized.]]>Gryglewicz, S. and W. Piechocki,2003873539Hwang, H. and S.Z. Erhan,20017811791184Schlosberg, R.H., J.W. Chu, G.A. Knudsen and E.N. Suciu,2001562126Uosukainen, E., Y. Linko, M. Lamsa, T. Tervakangas and P. Linko,19987515571563Wu, X., X. Zhang, S. Yangh, H. Chen and D. Wang,19987515571563Yunus, R., O.T. Lye, A. Fakhru'l-Razi and S. Basri,20027910751080Yunus, R., Fakhrul-Razi, T.L. OoiI, S.E. Iyuke and A. Idris,2003154249Yunus, R., Fakhrul-Razi, T.L. OoiI, S.E. Iyuke and A. Idris,2003153541