Journal of Applied Sciences1812-56541812-5662Asian Network for Scientific Information10.3923/jas.2007.1347.1350N, N-Dimethylbenzylamine and Its Complexes with Mo(CO)6 and W(CO)6]]>MahmudTariq IqbalJaved ImranMuhammad MckeeVickie 9200779The new ligand, 2-bromo-N, N-Dimethylbenzylamine has
been prepared according to scheme 1. The synthesized ligand
was further reacted with Mo(CO)6 and W(CO)6 to yield 2-bromo
N, N-Dimethylbenzylamine- Mo(CO)5 and 2-bromo N, N-Dimethylbenzylamine-W(CO)5
complexes, respectively. Both the ligand and its complexes were characterized
on the basis of physical properties, elemental analysis data, infrared and nuclear
magnetic resonance spectroscopy. It was found that the ligand has monodentate
nature and coordinates with metal through its nitrogen atom thus replacing one
CO molecule to maintain the charge density on metal centre.]]>Albert, J., J. Granell and R. Tavera,200322287291Beatrice, C., A. Maria and E. Ulli,20041018521857Farooq, H.M. and M. Z. Iqbal,199952139150Gao, H. and J.H. Angelici,199923633640Liang, H.C.,2003669182188Samina, K., C.J. Anwar, M. Arshad and K. Masud,200694853858Sert, S., O.S. Senturk and U. Ozdemir,20046 (M Cr, Mo, W), Re (CO) 5 Br, Mn (CO) 3 Cp] with Salicylaldehyde Methanesulfonylhydrazone.]]>57183188Tang, L.F. and P. Yang,2004293134Mahmud, T., J. Iqbal, M. Irshad, M.R. J. Elsegood and V. McKee,2005N, N-Dimethylbenzylamine) tungsten.]]>6117891791Yaman, S.O., E. Esenturk, C. Kayran and A.M. Onal,2002579298