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Pakistan Journal of Biological Sciences

Year: 2005 | Volume: 8 | Issue: 4 | Page No.: 512-519
DOI: 10.3923/pjbs.2005.512.519
Application of Oscillating Chemical Reaction to Analytical Chemistry: Recent Developments
Jinzhang Gao

Abstract: This mini-review is limited in the real application of oscillating chemical reaction to analytical chemistry and it covers the research published from 1999 to 2004; a few of papers appeared in the early of 2005 were also included. The most used system was the Belousov-Zhabotinksy (B-Z) reaction. Some of methods were designed based on the Cu (II)-catalysed oscillating chemical reaction. The analytes include both organic and inorganic substances. Simple and convenient, rapidness and good reproducibility are the characteristics of the present technique. Largely linear range and lower detection limit are of benefit to the use in the really routine analysis.

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How to cite this article
Jinzhang Gao , 2005. Application of Oscillating Chemical Reaction to Analytical Chemistry: Recent Developments. Pakistan Journal of Biological Sciences, 8: 512-519.

Keywords: Belosouv-Zhabotineky reaction, oscillating chemical system, analytical method and review

REFERENCES

  • Tikhonova, L.P., L.N. Zakrevskaya and K.B. Yasimirskii, 1978. Catalytic determination of ruthenium based on an oscillating chemical reaction. J. Anal. Chem., 33: 1991-1998.


  • Jimenez-Prieto, R., M. Silva and D. Perez-Bendito, 1995. Analyte pulse perturbation technique: A tool for analytical determination in far-from-equilibrium dynamic systems. Anal. Chem., 67: 729-734.


  • Jimenez-Prieto, R., M. Silva and D. Perez-Bendito, 1998. Approaching the use of oscillating reactions for analytical monitoring. Analyst, 123: 1-8.


  • Taylor, A.F., 2002. Mechanism and phenomenology of an oscillating chemical reaction. Prog. React. Kinet. Mech., 27: 247-325.


  • Li, Q.Z., X.H. Liu, J. Ren, H. Yang, W. Yang and J.Z. Gao, 2002. Effects of sodium diphenylamine sulfonate on the B-Z oscillating reaction. J. Northwest Normal Univ. (Nat. Sci.) (Ch.), 38: 51-54.


  • Fan, S.H., C.J. An, L. Zhuang, N.Q. Gan and Z.X. Lin, 1999. The effect of concentration of vitamin B1 on the B-Z oscillating chemical reaction and the kinetics. Acta Physico-Chimica Sinica (Ch.), 15: 178-181.


  • Gao, J.Z., J. Ren, W. Yang, X.H. Liu, H. Yang, Q.Z. Li and H.L. Deng, 2002. Kinetic determination of hydroquinone by Belousov-Zhabotinsky oscillating chemical reaction. J. Electroanal. Chem., 520: 157-161.


  • Gao, J., K. Sun, W. Yang, F. Yang and G. Zhao, 2004. Determination of benzidine using the analyte pulse perturbation technique in BZ oscillating chemical system. Pak. J. Biol. Sci., 7: 1721-1726.
    CrossRef    Direct Link    


  • Liu, X.H., J. Ren, H. Yang and J.Z. Gao, 2001. Kinetic determination of phenol by oscillating chemical reaction in open system. J. Instrut. Anal. (Ch.), 20: 9-11.


  • Lv, D.Y., J.Z. Gao, W. Yang and J. Ren, 2003. Kinetic determination of trace amount of resorcinol by B-Z oscillating chemical reaction. J. Northwest Normal Univ. (Ch.), 39: 48-50.


  • Gao, J.Z., Sounan, W. Yang, L. Wang, G.H. Zhao and K.J. Sun, 2004. Effect of ninhydrin on the B-Z oscillating chemical reaction. Chinese J. Anal. Lab. (Ch.), 23: 5-7.


  • Raoof, J.B., R. Ojani, A. Kiani, M. Khosravi and A. Adnani, 2005. The potentiometric effect of hydrazine on a B-Z oscillating chemical reaction: Application to the determination of hydrazine. Bull. Chem. Soc. Jap., 78: 258-261.


  • Toledo, R., M. Silva, V.O. Khavrus and P.E. Strizhak, 2000. Potential of the analyte pulse perturbation technique for the determination of polyphenols based on the Belousov-Zhabotinskii reaction. Analyst, 125: 2118-2124.


  • Ren, J., W. Yang, X.H. Liu, H. Yang, Q.Z. Li and J.Z. Gao, 2002. Perturbation of urine on the oscillating chemical system. J. Northwest Normal Univ. (Nat. Sci.) (Ch.), 38: 55-57.


  • Gao, J.Z., Q.Z. Li, W. Yang, X.H. Liu, J. Ren and H. Yang, 2004. Determination of rifampicin based on the BZ oscillating chemical reaction by the analyte pulse perturbation technique. Curr. Top. Electrochem., 10: 203-209.


  • Gao, J.Z., Sounan, W. Yang, L. Wang, G.H. Zhao and K.J. Sun, 2004. Effect of heroin on the B-Z oscillating chemical reaction and its analytical application. Chinese J. Anal. Chem. (Ch.), 32: 611-614.


  • Gao, J.Z., H. Yang, X.H. Liu, J. Ren, X.Q. Lu, J.G. Gou and J.W. Kang, 2001. Kinetic determination of ascorbic acid by the BZ oscillating chemical system. Talanta, 55: 99-107.


  • Dong, Y.J., K. Gai and X.X. Gong, 2004. Determination of nicotinamide adenine dinucleotide phosphate by B-Z oscillating chemical system. Chinese J. Anal. Chem., 32: 923-926.


  • Gao, J.Z., L.W. Sounan and W. Yang, 2004. Effect of barbituric acid on the B-Z oscillating chemical reaction and its analytical application. J. Northwest Normal Univ. (Nat. Sci.) (Ch.), 39: 62-65.


  • Berenstein, I. and D. Barragan, 2004. Additive effects of methyl ketones in the Belousov-Zhabotinsky reactions. J. Braz. Chem. Soc., 15: 844-848.


  • Zhang, Z.Q., C.J. An, Z.Z. Zhang, Y.Z. Zheng, D. Zheng and Z.Y. Wu, 2004. Kinetic study of chemical oscillatory reaction in the system of HCHO2-(malic acid)-BrO3G-Mn2+-H2SO4. J. Wuhan Univ. (Ch.), 50: 177-181.


  • Wang, J., S.T. Yang, R.X. Cai, Z.X. Lin and Z.H. Liu, 2005. A new method for determination of uric acid by the lactic acid-acetone-BrO3G-Mn2+-H2SO4 oscillating reaction. Talanta, 65: 799-805.


  • Yang, S.T., X.Z. Lin, R.X. Cai and N.Q. Gan, 2002. Determination of ascorbic acid using a new oscillating chemical system of latic acid-acetone-BrO3G-Mn2+-H2SO4. Chinese J. Chem., 20: 1019-1024.


  • Dong, Y.J., K. Gai and X.X. Gong, 2004. Kinetic determination of gibberellic acid by the BZ oscillating chemical system. J. Chinese Chem. Soc., 51: 7-11.


  • Yang, S.T., N.Q. Gan, X.Z. Lin and R.X. Cai, 2002. Determination of activity of anti-oxygenation of glutathione by the probe of the latic acid-acetone-BrO3G-Mn2+-H2SO4 oscillating system. Chem. J. Chinese Univ. (Ch.), 23: 1026-1029.


  • Cai, R.X., K. Zhang, W.H. Ma, N.Q. Gan and Z.X. Lin, 1999. Non-linear chemical reaction charactistics of diacetone-malic acid-BrO3G-Mn2+-H2SO4 and the application in biological anti-oxidation. J. Fuzhou Univ. (Ch.), 27: 49-50.


  • Gao, J.Z., J. Ren, W. Yang, X.H. Liu and H. Yang, 2003. Determination of caffeine using oscillation chemical reaction in a CSTR. J. Pharm. Biomed. Anal., 32: 393-400.


  • Yu, Y.O. and J.J. Jwo, 2000. Kinetic study of the Ce(III)-, Mn(II)-, or ferroin-catalysed Belousov-Zhabotinsky reaction with allylmalonic acid. J. Chinese Chem. Soc., 47: 433-439.


  • Field, R.J., E. Koros and R.M. Noyes, 1972. Oscillations in chemical systems. II. Through analysis of temporal oscillation in the bromate-cerium-malonic acid system. J. Am. Chem. Soc., 94: 8649-8664.


  • Yang, B., C.J. An, D. Zheng and Z.Z. Ding, 2002. Influence of NO2G on lactic acid-acetone-BrO3G-Mn2+-H2SO4 chemical oscillation reaction. Chinese J. Inorganic Chem. (Ch.), 18: 874-878.


  • Ojani, R., J. Raoof and F. Mahdavi, 2003. The potentiometric effect of As(III) ion on a Belousov-Zhabotinsky oscillating chemical reaction. Bull. Chem. Soc. Jap., 76: 2117-2121.


  • Liu, X.H., H. Yang, J.Z. Gao, Y.J. Ma and X.Q. Lu, 2001. Effect of fluoride on the B-Z oscillating reaction. Chinese J. Anal. Chem. (Ch.), 29: 1318-1321.


  • Yang, H., J.Z. Gao, W. Yang, X.H. Liu and G.H. Zhao, 2003. The effect of halogen on the B-Z oscillating chemical system. J. Northwest Normal Univ. (Nat. Sci.) (Ch.), 39: 45-48.


  • Raoof, J., R. Ojani and K. Kiani, 2004. Kinetic determination of silver ion by its perturbation on Belousov-Zhabotinsky oscillating chemical reaction using potentiometric method. Anal. Sci., 20: 883-886.


  • Strizhak, P.E., O.Z. Didenko and T.S. Ivashchenko, 2001. Determination of traces of thallium using the transient chaotic regime in the Belousov-Zhabotinskii oscillating chemical reaction. Anal. Chimica Acta, 428: 15-21.


  • Strizhak, P.E. and V.O. Khavrus, 2000. Determination of gases (NO, CO, Cl2) using mixed-mode regimes in the Belousov-Zhabotinskii oscillating chemical reaction. Talanta, 51: 935-947.


  • Gan, N.Q., R.X. Cai and Z.X. Lin, 2000. The effect of peroxide hydrogen on a chemical oscillating reaction. Anal. Sci., 16: 1327-1330.


  • Gao, J.Z., Q.Z. Li, W. Yang, X.H. Liu, J. Ren, H. Yang and H.L. Deng, 2002. Determination of L-valine based on an oscillating chemical reaction. Electroanalysis, 14: 1191-1196.


  • Gao, J.Z., H. Yang, X.H. Liu, J. Ren, Q.Z. Li and J.W. Kang, 2002. Determination of glutamic acid by an oscillating chemical reaction using the analyte pulse perturbation technique. Talanta, 57: 105-114.


  • Ren, J., J.Z. Gao, Sounan, G.H. Zhao, W. Yang, D.Y. Lv, K.J. Sun and C.Y. Li, 2004. Determination of heroin based on analyte pulse perturbation to an oscillating chemical reaction. Chem. Res. Chinese Univ., 20: 534-538.


  • Xiang, X.M., D.Y. Lv, J. Ren and J.Z. Gao, 2004. The effect of vitamin K3 on Cu(II)-H2O2-NaSCN oscillating chemical reaction. J. Northwest Normal Univ. (Nat. Sci.) (Ch.), 40: 53-56.


  • Gao, J.Z., L. Wang, W. Yang and F.W. Yang, 2005. Electrical potential oscillation in an anionic surfactant system with barbitone in octanol as an oil phase. J. Iranian Chem. Soc., 2: 71-77.
    CrossRef    Direct Link    


  • Gao, J.Z., K.J. Sun and W. Yang, 2003. Nonlinear behavior and domain feature at oil/water interface. Chinese Chem. Lett., 14: 1062-1065.


  • Yang, W., J. Ren, J.Z. Gao, H. Yang, D.Y. Lv and X.H. Liu, 2003. A novel chemical oscillator with tyrosine as the substrate. Chinese Chem. Lett., 14: 1281-1284.
    Direct Link    


  • Shen, S.G., C. Ynag, H.W. Sun, J.H. Shan and Y. Liu, 2003. The kinetic study of the chemical oscillating system of 1,3-propanediol/acetone as the organic substrate. Turk. J. Chem., 27: 243-250.
    Direct Link    


  • Strizhak, P.E., A.B. Basylchuk, I. Demjanchyk, F. Fecher, F.W. Schneider and A.F. Munster, 2000. Oxidation of ascorbic acid by air oxygen catalyzed by copper(II) ions in batch and continuous flow stirred tank reactors: Bistability, oscillations and stochastic resonance. Phys. Chem. Chem. Phys., 2: 4721-4727.
    CrossRef    Direct Link    

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