Trans-1.4-Isoprene Rubber as Hot Melt Adhesive
Abstract:
The use of maleic anhydride (MAH) modified and unmodified natural and synthetic trans-1.4-isoprene rubber (TIR Gutta Percha and TIR Synthetic) as hot-melt adhesives for plywood manufacturing under various glue spread levels was investigated and their gluability and durability in accordance to SNI 01-5008.2-99 standard were evaluated. TIR modified with MAH (MTIR) either natural (MTIR Gutta Percha) or synthetic (MTIR Synthetic) adhesives could reveal a satisfactory waterproof gluability. This is considered to be due to an enhanced adhesion caused by an occurrence of esterification between the hydroxyl groups of wood and the acid anhydride groups of MTIR during hot pressing. Infra red spectroscopic analysis showed both TIR Gutta Percha and TIR Synthetic have almost similar spectra. In the spectra of MTIR`s after purification, the peak at 1724 and at 1716 cm-1, respectively for MTIR Synthetic and MTIR Gutta Percha existed, indicated the characteristic for C=O of MAH. Differential thermal analysis showed that before and after modified with MAH, the melting and decomposition temperatures of MTIR Gutta Percha and MTIR Synthetic adhesives were quite different from TIR Gutta Percha and TIR Synthetic adhesives indicated that chemical modification of TIR`s with MAH were occurred. Either MTIR Gutta Percha or MTIR Synthetic adhesives are very appropriate for wood as hot melt adhesives.
How to cite this article
Fauzi Febrianto, Tati Karliati, Mohd Hamami Sahri and Wasrin Syafii, 2006. Trans-1.4-Isoprene Rubber as Hot Melt Adhesive. Journal of Biological Sciences, 6: 490-500.
REFERENCES
Albano, C., M. Ichazo, J. Gonzalez, M. Delgado and R. Poleo, 2001. Effects of filler treatments on the mechanical and morphological behavior of PP + wood flour and PP + sisal fiber. Mat. Res. Innovat., 4: 284-293.
CrossRef Direct Link
Alfa, A.A., A.M. Santosa and S. Honggokusumo, 1997. Gutta Percha: Moisture Content Problem and Solving. Indonesia Rubber Technology Research Centre, Bogor
Benu, S., H. Ismail, Husein and Krisnadhi, 1979. Reboisation of Protection Forest in Riau Province with Gutha Percha Tree. Vol. (9), Indonesian Forestry, Indonesia
Creswell, C.J., O.A. Runguist and M.M. Campbell, 1982. Analisis Spectrum Senyawa Organik (translated). Penerbit ITB., Bandung. Indonesia
Febrianto, F., M. Yoshioka, Y. Nagai, M. Mihara and N. Shiraishi, 1999. Composites of wood and trans-1,4-Isoprene rubber I: Mechanical, physical and flow behavior. J. Wood Sci., 45: 38-45.
Direct Link
Febrianto, F., M. Yoshioka, Y. Nagai, M. Mihara and N. Shiraishi, 2001. Composites of wood and trans-1.4- isoprene rubber II: Processing conditions for production of composites. J. Wood Sci. Technol., 35: 297-310.
Felix, J. and P. Gatenholm, 1991. The nature of adhesion in composites of modified cellulose fibers and polypropylene. J. Applied Polymer Sci., 42: 609-620.
Direct Link
Glasser, W., R. Taib, R. Jain and R. Kander, 1999. Fiber-reinforced cellulosic thermoplastic composites. J. Applied Polymer Sci., 73: 1329-1340.
Direct Link
Han, G.S., 1990. Preparation and physical properties of moldable wood-plastic composites. Ph.D. Thesis, Kyoto University, Japan. Unpublished, pp: 73-81.
Hedenberg, P. and P. Gatenholm, 1995. Conversion of plastic/cellulose waste into composites. I. Model of the interphase. J. Applied Polymer Sci., 56: 641-651.
Direct Link
Hofmann, W., 1989. Rubber Technology Handbook. Chapter 4, Hanser Publisher, New York, pp: 217-331
Indonesian National Standard, 1999. Plywood and block board for general purpose. SNI 01-5008.2-1999 standard. Indonesia National Standard Council, Jakarta.
Kazayawoko, M., J. Balatinecz and L. Matuana, 1999. Surface modification and adhesion mechanisms in wood fiber-polypropylene composites. J. Mater. Sci., 34: 6189-6199.
CrossRef Direct Link
Kim, T., Y. Lee and S. Im, 1997. The preparation and characteristics of low-density polyethylene composites containing cellulose treated with cellulase. Polymer Composites, 18: 273-282.
Direct Link
Kishi, H., M. Yoshioka, A. Yamanoi and N. Shiraishi, 1989. Composites of wood and polypropylene I. Mokuzai Gakkaishi, 34: 133-139.
Maldas, D. and B. Kokta, 1990. Influence of phthalic anhydride as a coupling agent on the mechanical behavior of wood fiber-polystyrene composites. J. Applied Polymer Sci., 41: 185-194.
Direct Link
Oksman, K., H. Lindberg and A. Holmgren, 1998. The nature and location of SEBS-MA compatibilizer in polyethylene-wood flour composites. J. Applied Polymer Sci., 69: 201-209.
Direct Link
Van de Velde, K. and P. Kiekens, 2001. Influence of fiber surface characteristics on the flax/polypropylene interface. J. Thermoplastic Comp. Mater., 14: 244-260.
Direct Link
© Science Alert. All Rights Reserved