Photocatalytic Activity under Solar Irradiation of Silver and Copper Doped Zincoxide: Photodeposition Versus Liquid Impregnation Methods
In this study, silver and copper doped zinc oxide photocatalysts were synthesized simply by Liquid Impregnation (LI) and Photo Deposition (PD) methods. The photocatalytic activities under solar irradiation for commercial azo dye degradation were observed. The photocatalysts with 0.5, 1.0, 1.5 2.0 and 2.5 % (mole ratio) metal versus ZnO was prepared. The photodegradation rates of the dye were estimated from the residual concentration at variable time detected by UV-Vis spectrophotometer. The experimental result shows that the Ag doped ZnO synthesized by PD method possess the highest photocatalytic activity while Cu doped ZnO synthesized by LI method has the reverse. The catalyst synthesized by PD method possesses more activity than another. The metal ion (Ag+/Cu2+) doped on ZnO acting as electron consumer leading to the lowering photocatalytic activity of the LI metal doped ZnO. The photocatalytic activity of all metal doped ZnO is in similar trend which increasing from 0.5-1.5 % mole ratio and decreasing afterward.
Received: March 08, 2012;
Accepted: August 03, 2012;
Published: September 04, 2012
To now, environmental problems such as air, soil and water pollution have provided
the motivation for research in the area of environmental treatment. One of the
most serious cause of water problem is from textile industries where produced
a large volume of colored dye effluents. Most of the dyes used in dyeing are
synthetic, toxic and non-biodegradable. Both physical and chemical processes
such as precipitation, adsorption, flocculation, reverse osmosis and ultra-filtration
were applied to remove these toxic substances in wastewater from production
process before releasing to environment. However, these techniques are non-destructive
process which the toxic substances are only removed and transferred. So, the
new type of pollution is rise and further treatment has also provided (Arslan
et al., 2000; Chaudhuri and Sur, 2000; Stock
et al., 2000).
Recently, photocatalytic techniques have been attracted much attention to be
one of the most interesting processes for wastewater treatment because of many
advantages over other traditional techniques such as convenient handle, quick
and low concentration (ppb level) oxidation and none of high toxic products
i.e., polycyclic aromatic compound are observed after photocatalytic process
has reached. The photocatalytic treatment for wastewater has been widely reported
(Qaradawi and Salman, 2002; Wang
et al., 2004; Liu et al., 2005, 2006;
Baiocchi et al., 2002; Kansal
et al., 2007; Bianco-Prevot et al., 2004;
Rizzo et al., 2009; Giraldo
et al., 2010; Lin and Lee, 2010; Selli
et al., 2008; Sanchez et al., 2011;
Son et al., 2009; Petrik
and Kimmel, 2010; Elmolla and Chaudhuri, 2010; Yang
et al., 2008).
TiO2 as well as ZnO have been considered as the promising photocatalyst
due to their high photocatalytic activity, photo-stability, wide-band gap and
less toxic. The quantum efficiency of ZnO is significantly higher than that
of TiO2 (Mai et al., 2008). The better
activity of ZnO than TiO2 was reported in some cases (Chen,
2007). The ZnO-mediated photocatalytic process has been successfully used
to organic pollutant degradation (Height et al.,
2006; Akyol et al., 2004). Due to it is available
at low cost and absorbs over larger fraction of the solar spectrum than TiO2
(Christoskova and Stoyanova, 2001), thus ZnO is considered
as suitable material for photocatalytic degradation of organic pollutants than
TiO2. However, many studies have been reported the photocatalytic
activity of TiO2 photocatalyst for either dye degradation or antimicrobial
activity (Fatimah et al., 2009; Zulfakar
et al., 2011; Qourzal et al., 2006;
Tchatchueng et al., 2009; Desai
and Kowshik, 2009). Previous studies have reported the photodegradation
of organic pollutants by ZnO (Mansilla et al., 1994;
Ohnishi et al., 1989; Peralta-Zamora
et al., 1998; Richard et al., 1997)
and removal of color from landfill by solar photocatalytic system by using ZnO
photocatalyst was also reported (Makhtar et al.,
|| Solar irradiation pattern of the month of December 2011
However, the main problem for the photocatalytic process is due to the fast
recombination of the electron-hole pairs. This situation is a cause of deceasing
of photocatalytic activity of the photocatalyst. Doping of transition metals
on the photocatalyst surface (Wood et al., 2001;
Stroyuk et al., 2005) as well as coupling of
two photocatalysts can improve the charge-transfer and photocatalytic activity.
In this study, the photocatalytic degradation of reactive synthetic dye using
Ag and Cu doped ZnO photocatalysts synthesized by convenient photodeposition
and liquid impregnation methods were reported. The photodegradation efficiency,
kinetics as well as rate constants related to the loading contents of metals
on ZnO were reported.
MATERIALS AND METHODS
Materials: The commercial azo anionic dye, C.I acid red 142 (C.I. No. 6406-66-2) is a model of organic dye pollutant for textile industry. ZnO powder (analytical grade) was purchased from RFCL limited, the analytical grade AgNO3 and Cu(NO3)2.3H2O were purchased from Merck and QRëC companies, respectively.
Preparation of silver doped ZnO photocatalyst
Liquid impregnation method: The silver doping on ZnO by LI method
was prepared in this following step. Firstly, 3 g of ZnO was added to 100 mL
deionized water. The amount of AgNO3/Cu(NO3)2.3H2O
with 0.5, 1.0, 1.5 2.0 and 2.5% (mole ratio) versus ZnO was required to add
into ZnO slurry. The slurry was stirred well and rest for 24 h (performed in
darkness) and then dried in an air oven at 100°C for 12 h. the dried solids
were grounded in an agate mortar and calcined at 600°C for 6 h in a furnace.
Photodeposition method: For PD method, 3 g of ZnO was added to 100 mL deionized water. The amount of AgNO3/Cu(NO3)2.3H2O with 0.5, 1.0, 1.5, 2.0 and 2.5% (mole ratio) versus ZnO was required to added into ZnO slurry. The slurry was stirred well under solar irradiation for 3 h and then dried in an air oven at 100°C for 12 h. The dried solids were grounded in an agate mortar and calcined at 600°C for 6 h in a furnace.
Photocatalytic activity under solar radiation: For the photocatalytic degradation of acid red 142 dye, a 1 ppm dye solution containing 1 g of different types of metal doped and undoped ZnO were prepared and agitated for 30 min in darkness. A 100 mL of the solution mixture was transferred into the batch reactor. The reaction was initiated when the solution mixture was exposed to the solar irradiation. The solution was stirred well during the reaction progress. The residual of the dye in solution was measured by the absorption at 620 nm by UV-Vis spectrophotometer (T80+model UV-Vis spectrophotometer, PG Instruments Ltd). The degradation efficiency is calculated using the following equation:
where, C0 and C represent the initial and variable concentrations while A0 and A are initial and variable absorbance, respectively. Concentration of the dye remaining in solution was received from the standard curve.
Solar irradiation condition: Due to performing under solar condition, the solar irradiation pattern was monitored in the month of December 2011 from 10.00 a.m. to 3.00 p.m. The solar light intensity was measured by Lux-UV-IR meter (LX-72, DIGICON). The solar light intensity was recorded on every reaction time during experiment performed as shown in Fig. 1. The radiation of more than 1000 W m-2 was recorded on all the experimental days. The experiments were not carried out on the days with solar intensity of less than 1000 W m-2.
RESULTS AND DISCUSSION
The photocatalytic process of the metal doped (Ag/Cu) ZnO is represented in
Fig. 2. The photocatalytic mechanism of Ag/Cu doped ZnO can
be proposed as follows (Chen et al., 2008; Zheng
et al., 2007; Wang et al., 2007):
The basis of photocatalytic activity of Ag/Cu doped ZnO can be summarized that;
(1) ZnO acts as an electron and hole sources (Eq. 1) for degradation
of dye. The electron in Valence Band (VB) was excited to conduction band by
UV light with equal or higher energy than energy band gap of ZnO leading to
simultaneous generation of a hole (h+) in VB, (2) oxygen vacancy
defects (V*o and V*o in Eq. 2, 3)
and Ag/Cu nanoparticles on the ZnO surface act as a sink for electron and improve
of the electron-hole pair separation generated in Eq. 1, (3)
photoelectron can be easily trapped by acceptors such as molecular oxygen forming
superoxide radical anion (O-C2) as shown in Eq.
5, (4) The photoinduced hole can be easily trapped by OH¯ as well as
H2O to produce OH• (Eq. 7, 8),
(5) The generated O-C2 can react with H2O forming
H2O2 and then reacts with forming OH•
(Eq. 9, 10) and (6) The overall photocatalytic
reaction is due to the oxidation reaction between these generated reactive oxygen
species (O-C2 and OH•) and pollutant
i.e., synthetic dye (Eq.11).
||Mechanism of photocatalytic process of Ag/Cu doped ZnO under
The enhancement of photocatalytic activity based on metal doping ZnO is depend
upon the additional rate of O-C2 and OH•
formations (Eq. 3, 5,10).
In addition, the rate of electron transfer from VB of ZnO to deposited Ag/Cu
should also be faster than those of electron-hole pair recombination. The photocatalytic
activity as well as key mechanism concerning to the photocatalytic process of
Ag doped ZnO has been observed and proposed (Zhang, 2011).
It has been concluded that Ag particle deposited on ZnO surface acting as electron
traps to effectively separate the excited electron-hole pairs. This can be supported
the mechanisms presented above.
Effect of Ag and Cu doping on photocatalytic activity of ZnO: The photocatalytic
activity of undoped and metal doped ZnO was carried out without adjustment of
pH. The photodegradation of acid red 142 in the presence of undoped and metal
doped ZnO powder under solar radiation versus irradiation time was shown in
Fig. 3. As can been seen, the Ag doped ZnO synthesized with
both PD and LI methods are generally more efficient in photodegradation of the
dye than Cu doped ZnO. The metal doped ZnO with PD is more effective than those
of LI method. In a period of initial to 1 h, all metal doped ZnO showed percentage
photodegradation of the dye higher than those of the undoped one except for
1.5:1 and 2:1 LI Cu dope ZnO but in a reverse afterward except for PD Ag doped
ZnO. It can be noted that the metal doping can accelerate the photocatalytic
activity of ZnO within 1 h of photocatalytic experiment. The different photocatalytic
activity of the metal doped ZnO synthesized by the two methods can be ascribed
in term of oxidation state of the metals. During the preparation process by
PD method, the Ag+ and Cu2+ were reduced to Ag and Cu
but on the other hand, Ag+ and Cu2+ were deposited directly
on the ZnO surface by LI method.
||Percent degradation of acid red 142 by, (a) LI Ag doped, (b)
PD Ag doped, (c) LI Cu doped and, (d) PD Cu doped ZnO
||Pseudo-first-order kinetics for photodegradation of acid red
142 by (a) LI Ag doped (b) PD Ag doped (c) LI Cu doped and (d) PD Cu doped
The deposited Ag+ and Cu2+ consumes electron during the
photocatalytic process leading to the decreasing of photocatalytic activity
of metal doped LI ZnO. This can be stated that the electron transfers from ZnO
to Ag+ or Cu2+ is rather fast regarded to the electron
transfer to the dissolved oxygen molecules, so therefore the formation of O-C2
is reduced (Szabo-Bardos et al., 2003).
Based on the Ag doped PD method, the best photocatalytic activity in comparison
to undoped ZnO was found. This indicated that the electron-hole pair charge
recombination was competed with the electron transfer for ZnO to Ag atom. In
case of Cu doping, both PD and LI Cu doped ZnO powders possess a little bit
higher photocatalytic activity in comparison to undoped one. Consider of the
standard reduction potential, Cu2+ requires 0.15 V while Ag+
requires only 0.80 V to form their zero oxidation states. The doping of Cu based
on PD method is lesser completed than those of Ag, therefore Cu+
may be mostly deposited instead of Cu atom leading to decreasing of photocatalytic
||The rate constants based on pseudo-first-order kinetics for
photodegradation of acid red 142 by metal doped ZnO versus mole ratio of
It can be noted that the deposition of metal ion (Ag+/Cu2+;
LI method) affected negatively to the photocatalytic activity of ZnO compared
to another one (Ag/Cu; PD method) because the ions act as electron consumer
instead of electron donor.
Kinetics of photodegradation: Kinetics of photodegradation of
the dye by all metal doped and undoped ZnO assumed to be pseudo-first-order
reaction indicated by the strength line of the plot between lnC0/C
and irradiation time as shown in Fig. 4. Based on the strength
line, rate constant can be calculated and the relationship between rate constants
and mole ratio of metal doping are plotted in Fig. 5. It was
found that all metal doped ZnO has pseudo-first-order kinetic rate constant
generally higher than those of the undoped ZnO. The low rate constant 43 min-1
was found for undoped ZnO due to its slowly initial reaction. It can be seen
that Ag and Cu contents loading on ZnO surface have the maximum value of 1.5%
for both Ag and Cu doped ZnO. The rate constant of photodegradation of the dye
by Ag and Cu doped ZnO is increasing up to 1.5:1 mole ratio then decreasing
afterward. The highest rate constant (~ 250 min-1) was found in PD
1.5:1 Ag doped ZnO. Based on 1.5:1 mole ratio metal: ZnO, the kinetic rate (min-1)
for all metal doped ZnO are in decreasing order: PD Ag (246) > LI Ag (98)
> PD Cu (78) > LI Cu (54). The effect of Ag and Cu doping on ZnO photocatalytic
activity may be caused from several reasons as previously discussed for Ag doped
TiO2 (Benhnajady et al., 2008), Excessive
coverage of metals on ZnO limits the light reaching to ZnO surface, reducing
the number of photogenerated electron-hole pairs, leading to the decreasing
of ZnO photocatalytic activity (Carp et al., 2004).
Negatively charge metal sites have attracted holes and subsequently recombined
with electrons, therefore the negatively charge Ag/Cu sites are the charge recombination
center (Carp et al., 2004). Metals may occupy
the active site on ZnO surface for a desired photocatalytic reaction, causing
of losing photocatalytic activity of metal doped ZnO (Coleman
et al., 2005). The probability of the hole capture is increased by
a large number of metal particles at high content loading, in this case the
probability of holes reacting with the adsorbed species i.e. H2O
or H2O2 is decreased (Sobana et
Previously, porous Ag doped ZnO microrods were synthesized and photocatalytic
activity over methyl orange degradation observed (Jia et
al., 2012). It was found that 3% (mole fraction) of Ag loaded on ZnO
reached the highest activity. Similarly, photodegradation of methyl orange by
Ag doped ZnO with 65% dye removal achieved within 100 min was observed (Zhang
and Zeng, 2010). The Ag loaded ZnO photocatalyst with 3% Ag loading was
observed and possessed the highest rate of rhodamine 6G degradation (Geofgekutty
et al., 2008). The 0.5% Ag loaded ZnO possessed the highest rate
of photocatalytic activity for AR88 textile dyes degradation has been observed
(Behnajady et al., 2009). Ag doped ZnO with precursor
zinc nitrate hexahydrate by applying hybrid induction and laser heating techniques
has been synthesized and determined its activity for DBP degradation (Qi
et al., 2011). Thus, it can be noted that the photocatalytic activities
of various% Ag doped ZnO is depended upon the methods of synthesis and starting
reagents. In addition, Ag doped ZnO-SnO2 co-catalyst has been also
shown the better photocatalytic activity than those of the undoped ZnO-SnO2
at photocatalytic degradation of AR27 dyes (Behnajady
et al., 2010).
The Ag and Cu doped ZnO powders were synthesized simply by two methods; photodeposition and liquid impregnation with 0.5, 1.0, 1.5 2.0 and 2.5% mole ratio (metal:ZnO). The metal doped ZnO synthesized by PD method possesses more photocatalytic activity than those by LI method. The decreasing photocatalytic activity of the LI metal doped ZnO due to the consumption of electron by the deposited metal ions during the photocatalytic process. However, generally, all metal doped ZnO shows the pseudo-first-order kinetic rate of photocatalytic degradation higher than those undoped ZnO except for 0.5:1 and 1:1 LI Cu doped ZnO. The photocatalytic activity of metal doped ZnO is increased from 0.5 to 1.5% mole ratio and decreased afterward. It can be stated by several reasons as described in the results and discussion part.
This study was financially supported by Faculty of Engineering, Rajamangala University of Technology Isan, Khon Kaen Campus. Phisit Intergroup Co., LTD, Bangkok was gratefully acknowledged for giving C.I. acid red 142 dye used in this work.
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