Influence of Nanoclay/Phenol Formaldehyde Resin on Wood Polymer Nanocomposites
Md. Rezaur Rahman,
Md. Saiful Islam
Abu Saleh Ahmed
Selected tropical wood specie was low dense soft wood and it is abundantly available in Borneo Island. This specie is not suitable for construction materials due to their law physical and mechanical properties. In order to overcome this problem the wood species were impregnate by Nanoclay/PF resin system. Raw wood specimens were then placed into an impregnation chamber, in which there was no contact between samples and they were covered completely by nanoclay/PF mixtures. The system was evacuated to 60 mmHg for 30 min. After that, compressed air was applied to the system and maintained at a pressure of 0.52 MPa for 30 min then released. The excess chemicals wiped off the samples. FT-IR spectra indicate the decrease wave number of the peak, ascribed to C-O stretch of C-O-H in starch at 1317 cm-1 and 1222 cm-1 and C-O stretch of C-O-C in starch at 1027 cm-1 confirmed the impregnation of nanoclay/PF wood sample due to the fact that plasticizer could form intense H-bonding interaction with the hydroxyl groups. The MOE and MOR of WPNC were significantly increased compared with raw wood. The Youngs modulus of Eugenia sp. was significantly different between raw wood and WPNC. The XRD patterns of WPNC indicate that the crystallinity increases at the amorphous region due the monomer loading. The SEM micrograph of WPNC clearly shows the void space was filled by the monomer and removes the waxy substance.
Received: November 06, 2011;
Accepted: June 18, 2012;
Published: August 01, 2012
Organic or inorganic fillers have been used as reinforcements in polymers.
The up to date nanoparticles has attracted much attention in manufacturing polymeric
nanocomposites using various nanoparticles as reinforcements. The polymeric
nanocomposites showed their different properties based on the experimental results.
Some researcher found the improvement of the matrix properties (Lee
et al., 2011; Hamzah et al., 2010;
Ratnasingam and Ioras, 2010; Ramasamy
and Ratnasingam, 2010; Adebhar et al., 2001;
Yasmin et al., 2003; Kinloch
et al., 2003) while others reported unfavorable effect (Haggenmueller
et al., 2006; Zilg et al., 1999, 2000)
due to the additions of nanoparticles. Moreover, the effect of nanofillers is
established its necessity because of its unique properties and reliable method
of dispersing nanoparticles is still lacking.
In order to overcome this problem nanoparticles break these bunches and established
the shear mixing methods. (Nazerian et al., 2011a;
Hng et al., 2011; Yasmin
et al., 2003), mechanical mixing (Shah and Paul,
2004), in situ polymerization (Haggenmueller
et al., 2006; Nazerian et al., 2011b;
Farrokhpayam et al., 2010; Ratnasingam
et al., 2010a, b) and impregnation have been
used to produce nanocomposites. Researchers have been reporting improved mechanical
properties of nanocomposites fabricated via the impregnated method. However,
with few exceptions, the properties of the resulting nanocomposites tend to
go down after reaching the maximum at a particle loading of about 3-5 wt.% or
less (Rodgers et al., 2005; Choi
et al., 2005; Zheng et al., 2005).
Some articles have been published on silica/epoxy nanocomposites fabricated
from organosilicasol (colloidal silica in organic solvent) (Adebhar
et al., 2001; Kinloch et al., 2003;
Uddin and Sun, 2008). Uddin and
Sun (2008) obtained 40% improvement in matrix compressive modulus with 15
wt.% silica nanoparticle loading. By using this nanoparticle-enhanced matrix,
glass fiber composites gained 60-80% in longitudinal compressive strength for
different fiber volume fractions. Kinloch et al.
(2003) reported the greatly improved fracture behavior of an epoxy adhesive
with the inclusion of both silica nanoparticles and rubber composites. In this
study Nanoclay/Phenol Formaldehyde resin system were used as a reinforcement
matrix to produce the WPNC.
MATERIALS AND METHODS
Materials: The softwoods Eugenia sp., Artocarpus rigidus, Artocarpus elasticus and Xylopia sp. and the hardwood Koompassia malaccensis were used for this study since June 2011 to end of December 2011. Chemicals used to impregnate these wood species were Nanoclays nanomer® 1.30E, Montmorillonite (MMT) (Southern Clay Products, Inc. USA) and Phenol Formaldehyde resin (PF) (Merck, Germany). The purity grade of the chemicals were 99%.
Preparation of impregnation solutions: The impregnation solutions were prepared by adding 1% layered aluminosilicate nanofiller into the low viscosity phenol formaldehyde resin at a mixing speed of 2050 rpm for 20 min then nanoclays were mixed with the PF resin prepolymer to form impregnation solutions that were subsequently used to impregnate the wood species.
Manufacturing of wood polymer nanocomposites: Raw wood specimens were oven dried to constant weight at 103°C for 24 h. They were then placed into an impregnation chamber, in which there was no contact between samples and they were covered completely by nanoclay/PF mixtures. The system was evacuated to 60 mm Hg for 30 min. After that, compressed air was applied to the system and maintained at a pressure of 0.52 MPa for 30 min then released. The excess chemicals were wiped off the samples. Specimens were weighted and dried 24 h by air circulation, followed by oven drying at 90°C for 24 h. The excess polymers were then removed from the surface.
FT-IR spectroscopy analysis: The infrared spectra of the raw woods and WPC were recorded on a Shimadzu Fourier Transform Infrared Spectroscopy (FTIR) 81001 Spectrophotometer. The transmittance range of the scan was 370 to 4000 cm-1.
The free- free flexural vibration testing: Determination of the dynamic Youngs modulus (Ed) was carried out using the free-free flexural vibration testing system. The specimen was held with AA thread according to the first mode of vibration. The specimen with an iron plate bonded at one end was set facing the electromagnet driver and a microphone was placed at the centre below the specimen. The frequency was varied in order to achieve a resonant or natural frequency. The Ed was calculated from the resonant frequency by using the following equation:
where, I is bd3/12, d is beam depth, b is beam width, l is beam length, f is natural frequency of the specimen, ρ is density, A is cross sectional area and n = 1 is the first mode of vibration, where m1 = 4.730.
Determination of static Youngs modulus (Es), modulus of
elasticity (MOE) and modulus of rupture (MOR): Determination of Es,
MOE and MOR was carried out according to ASTM D-143 (2006).
A Shimadzu Universal Testing Machine having a loading capacity of 300 kN was
used for the test with the cross head speed of 2 mm/min. Es was measured
using the uniaxial compression test. The MOE and MOR were measured using the
three point bending method and were calculated using the following equations,
||Span length of sample, 180 mm
||Width of sample, 20 mm
||Thickness of sample, 20 mm
||Slope of the tangent to the initial line of the force displacement curve
||The maximum breaking load
||Depth of the beam
Scanning electron microscopy analysis (SEM): The specimens were first
fixed with Karnovskys fixative and then taken through a graded alcohol
dehydration series. Once dehydrated, the specimen was coated with a thin layer
of gold before being viewed on the Scanning Electron Microscope (JSM-6701F)
supplied by JEOL Company Limited, Japan. The micrographs, taken at a magnification
X-ray diffraction analysis (XRD): XRD analysis for raw wood and Wood Polymer Composites (WPC) were performed with a Rigaku diffractometer (CuK α radiation, λ = 0.1546 nm) running at 40 kV and 30 mA.
RESULTS AND DISCUSSION
Fourier transforms infrared (FTIR) spectroscopy analysis: FTIR spectra
of raw wood and WPNC are shown in Fig. 1. The spectra were
separated in two regions, namely: the OH stretching vibrations in 4000-2700
cm-1 region and fingerprint region in 1800-400 cm-1 region.
|| IR spectrum of (a) Raw wood and (b) WPNC
The stretching band of OH group and C-H group was 3300-4000 cm-1
and 2800- 3000 cm-1, respectively. The band region from 1000 to 1750
cm-1 shown the superposition with sharp and discrete absorptions
(Owen and Thomas, 1989). The absorption band 1508 cm-1
is caused by lignin and the absorption located at 1735 cm-1 is caused
by hemicelluloses. This indicates the C = O stretch in non-conjugated ketones,
carbonyls and ester groups (Owen and Thomas, 1989).
The region between 1800 and 1100 cm-1 comprises bands assigned to
the main components from wood: cellulose, hemicelluloses and lignin. Clear difference
can be detected in the infrared spectra, both in the different absorbance values
and shapes of the bands and their location. The less xylan content in softwood
is evidenced by a carbonyl band at 1735 cm-1, for nanoclay/PF modified
wood, this being shifted to a lower wave number value (1591 cm-1).
On the other hand, the decrease wave number of the peak, ascribed to C-O stretch
of C-O-H in starch at 1317 and 1222 cm-1 and C-O stretch of C-O-C
in starch at 1027 cm-1 confirmed the impregnation of nanoclay/PF
wood sample due to the fact that plasticizer could form intense H-bonding interaction
with the hydroxyl groups.
Dynamic Youngs modulus measurement: The dynamic Youngs modulus
of the raw wood and WPNC, from the free-free flexural vibration testing system
is shown in Fig. 2. Ten specimens were used for each species.
The nanofiller with phenol formaldehyde monomer system increased the Youngs
modulus, as seen in all species which was according to our previous work (Hamdan
et al., 2010). After monomer impregnation the Youngs modulus
of Eugenia sp., Xylopia sp., Artocarpus rigidus and Artocarpus
elasticus, were significantly higher than that of raw one. On the other
hand the Youngs modulus of Koompassia malaccensis was slightly
higher due to their hard cell wall (due to the nanofiller effect on all wood
||Dynamic Youngs modulus of raw wood, WPNC for all species
|| MOE of raw wood and WPNC
Modulus of Elasticity (MOE) and modulus of rupture (MOR) measurement:
The MOE and MOR of raw wood and WPNC are shown in Fig. 3 and
4, respectively. The nanofiller phenol formaldehyde monomer
system impregnation on the discerning wood species was investigated. The increment
in MOE of the Eugenia sp. and Xylopia sp. were highest followed
by, Artocarpus rigidus, Artocarpus elasticus and Koompassia malaccensis,
respectively. WPNC yielded higher MOE compared to the raw wood because of the
impact of nanofiller on wood species which is in accordance with other researchers
(Cai et al., 2007, 2008).
From Fig. 3, the MOE of the Eugenia sp., Xylopia sp., Artocarpus elasticus and Artocarpus rigidus were significantly higher compared with raw wood. However in Koompassia malaccensis, (hardwood) there was no significant effect of nanomer impregnation but increment in MOE was slightly higher than that of our previous work.
|| MOR of raw wood and WPNC
In the wood specimens, phenol formaldehyde plasticizes on the cellulose and hemicellulose in wood cells which reduces the water molecules from the wood specimens. During the nanoclay phenol formaldehyde monomer impregnation nanofiller react as a binder which fill the void space in the wood specimens and increase it stiffness. For this reason the MOE of all WPNC was higher than that of raw wood (Fig. 3).
The MOR of Eugenia sp. WPNC was radically increased after nanofiller
with phenol formaldehyde impregnation. The MOR also improved after nanofiller/phenol
formaldehyde impregnation in accordance with previous research (Cai
et al., 2007, 2008).
Figure 4 indicates that the MOR was significantly different for Xylopia sp., Artocarpus rigidus, Artocarpus elasticus and Eugenia sp. raw wood and WPC. The growth of MOR for Eugenia sp. was highest followed by Xylopia sp., Artocarpus rigidus, Artocarpus elasticus and Koompassia malaccensis, respectively. The value for Koompassia malaccensis (hardwood) WPNC was higher than that of raw one.
Static Youngs modulus (Es) measurement: The Static
Youngs modulus was determined from 10 repetitions, as summarized in Fig.
5. The highest increment of Es value was observed in Eugenia
sp. followed by Artocarpus rigidus, Artocarpus elasticus, Xylopia sp.
and Koompassia malaccensis, respectively. Figure 5
indicates that, the increment of Es between raw wood and WPNC for
Eugenia sp. was significantly different. The increment of Es
in WPNC compared to raw wood was also reported by different researchers (Cai
et al., 2007, 2008; Rahman
et al., 2010). The nanofiller/phenol formaldehyde not only plasticized
on the wood cell walls but also deeply increasing their lateral stability.
||Static Youngs modulus of raw wood and WPNC
XRD analysis: Figure 6 presents the results of XRD
for raw wood and WPNC. The spectrum corresponding to the raw wood and WPNC shows
diffraction peaks at the following 2θ angles: 17°, 22.5° and 35°
which correspond to the cellulose crystallographic planes 101, 002 and 040,
respectively (Mulinari et al., 2010). The position
of these peaks did not change which indicates that the structure of cellulose
did not change in comparison with the raw wood. It is observed that the WPNC
exhibited another five broad 2θ peaks at 43.74°, 49.21°, 51.13°,
55.65° and 72.87° which are due to increasing polymerization in the
These values can be attributed to modification of the wood by the nanofiller/phenol-formaldehyde
prepolymer. The reason may be that the prepolymer has been injected into the
lumen of wood cell. The crosslinking reaction occurred between the groups of
prepolymer and the surface hydroxyl (OH) groups of wood. A quasi-crystalline
form was generated in the XRD, but actually it may not represent an increase
in the crystallinity of cellulose (Wu et al., 2004).
Scanning electron microscopy (SEM) analysis: Scanning Electron Micrographs
(SEM) of raw wood and WPNC are shown in Fig. 7. The SEM micrographs
showed that the raw wood surfaces were covered with an uneven layer with a number
of void/hole spaces, while the treated wood surfaces were smooth (Fig.
7a, b). The smooth surface may be caused by the good penetration
of the monomer mixture to the cell wall and vessels of the wood (Rahman
et al., 2010). The SEM analysis indicated that the prepolymer was
impregnated into cell wall and cell cavities of wood.
In the present study nanofiller/phenol formaldehyde WPC were investigated. FT-IR spectra indicate the decrease wave number of the peak, ascribed to C-O stretch of C-O-H in starch at 1317 cm-1 and 1222 cm-1 and C-O stretch of C-O-C in starch at 1027 cm-1 confirmed the impregnation of nanoclay/PF wood sample due to the fact that plasticizer could form intense H-bonding interaction with the hydroxyl groups. The stiffness of the WPNC was significantly increased compared with raw wood. The MOE and MOR of WPNC were significantly increased for Eugenia sp., Xylopia sp., Artocarpus Rigidus and Artocarpus Elasticus respectively. The Youngs modulus of Eugenia sp. was significantly different between raw wood and WPNC. The XRD patterns of WPNC indicate that the crystallinity increases at the amorphous region due the monomer loading. The SEM micrograph of WPNC clearly shows the void space was filled by the monomer and removes the waxy substance. It can be concluded that nanofiller/phenol formaldehyde was significantly effective on Eugenia sp. followed by Xylopia sp., Artocarpus Rigidus and Artocarpus Elasticus wood species, respectively.
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