Purification of Natural Gas with High CO2 Content by Formation of Gas Hydrates: Thermodynamic Verification
High carbon dioxide (CO2) content in natural gas may constitute some environmental hazards when release to the atmosphere. A variety of conventional separation methods are presently being used to remove the undesired gas fraction from crude natural gas. One promising approach to capture CO2 from natural gas is by formation of gas hydrate. Gas hydrates can be formed in a system containing water and small molecule gases such as CH4 and CO2 at appropriate pressure and temperature conditions. It is important to gain accurate data of the phase behavior of the gas hydrate forming systems to ensure that the process conditions are set in hydrate forming conditions. In this study, thermodynamics modeling approached is implemented to generate the phase equilibria data since the phase behavior measurements are often expensive, tedious and time consuming processes. The thermodynamic program, CSMGem is successfully used for prediction of equilibrium conditions for single and binary hydrate former systems with AAD% is less than 10%. The program is being further used to predict gas hydrate equilibrium for natural gas with different concentration of CO2.
Received: February 17, 2011;
Accepted: April 15, 2011;
Published: December 16, 2011
Nowadays, natural gas has become an important source of energy and feedstock
for chemical industries (Scholz et al., 1981; Xiao
et al., 2009). Natural gas is a mixture of combustible gases formed
underground by the decomposition of organic materials in plant and animal. Raw
natural gas is composed of several gases. The main component is methane and
it also contains varying amounts of heavier hydrocarbons, acid gases, water,
mercury and inert gases (Mokhatab et al., 2006).
Malaysia has the largest natural gas reserved among the Southeast Asian economies
and is the third largest amongst the Asia Pacific economies. As per 1st January
2000, the recoverable reserves of Malaysian natural gas stand at 84.4 trillion
standard cubic feet of which 48% is located at offshore Sarawak, 43% offshore
east coast of Peninsular Malaysia and the remaining 9% at offshore Sabah. These
large gas reserves are sufficient to last around 43 years with current production
rate (Zulkifli et al., 2002).
In natural gas, non-hydrocarbon gases (CO2, N2, H2S)
can account between 1 to 99% of overall composition (Thrasher
and Fleet, 1995). High CO2 concentrations are encountered in
diverse areas including South China Sea, Gulf of Thailand, Central European
Pannonian basin, Australian Cooper-Eromanga basin, Colombian Putumayo basin,
Ibleo platform, Sicily, Taranaki basin, New Zealand and North Sea South Viking
Graben (Thrasher and Fleet, 1995). The composition of
CO2 can reach as high as 80% in certain natural gas wells such as
wells at the LaBarge reservoir in western Wyoming and the Natuna production
field in Indonesia (Holder et al., 1988).
Due to stringent regulation on CO2 content in commercial natural
gas, high CO2 content in natural gas has to be removed. Various methods
for removing CO2 have been suggested such as cryogenic fractionation,
selective adsorption, gas absorption and membrane process. Although some of
these processes have proved successful for the selective removal of CO2
from multi-component gaseous streams, they still have some critical problems
associated with large energy consumption, corrosion, foaminess and low capacity
(Kang and Lee, 2000). Moreover, the current technologies
cannot purify CO2 effectively when CO2 increase to 50-80%
in the natural gas stream. Hence, new separation technology which is environmental
friendly and with low operational cost must be developed to cater for the separation
of CO2 from this high CO2 content natural gas. One promising
approach to capture CO2 from natural gas is through gas hydrate formation.
When gas hydrates are formed from natural gas, the concentrations of natural
gas components in hydrate phase are different than that in the original gas
Gas or clathrate hydrates are ice-like crystalline compounds which are formed
through combination of water and small guest molecules like CH4,
CO2, etc. under suitable conditions of low temperature and high pressure
(Sloan and Koh, 2008). In a gas hydrate molecule, water
forms special cavities and guest molecules are trapped inside the cavities.
Depending on the type and size of guest molecule presents, different gas hydrate
structures can be formed.
The three most common types of clathrate hydrate: structure I (sI), structure
II (sII) and structure H (sH) have been well defined by Sloan
and Koh, 2008. The type of hydrate that forms will highly depend on the
composition of the gases in the feed as well as temperature and pressure of
Over the last decade, the interest in using clathrate hydrates formation as
separation method or storage and transportation medium has revived, especially
for natural gas and CO2. In literature, separation of CO2
from gas streams and its sequestration in geological formation by gas hydrate
formation have been widely studied by Sabil et al.
(2010a,b). When gas hydrates are formed from natural
gas, the concentrations of natural gas components in hydrate phase are different
than that in the original gas mixtures. For example, in the case of methane-carbon
dioxide (CO2-CH4) mixture, the hydrate phase will be richer
in CO2 than that CH4 at certain condition (Kang
and Lee, 2000). This selective information is the basis for utilization
of gas hydrate formation as a separation process.
In order to successfully implement the hydrate formation as a method for separation of CO2 from natural gas stream, the phase equilibria data need to be determined. The phase boundaries will limit the region in which this technology can be used for the separation process. In this study, thermodynamics modeling approached is implemented to generate the phase equilibria data since the phase behavior measurements are often expensive, tedious and time consuming processes. Since the modeling approached has been selected, a verification of the model is initially with some available literature data for single hydrate former system. The AAD% is calculated between the experimental and the modeling results. Once the model is proven suitable, the model is used to generate data for the binary and multi components systems.
The pressure and temperature conditions for the formation or dissociation of
gas hydrate are governed by the thermodynamic equilibrium (Sloan
and Koh, 2008). A system is in thermodynamic equilibrium when it is in thermal,
mechanical and chemical equilibrium. For a system at constant pressure and temperature,
thermodynamic equilibrium can be characterized by the minimization of Gibbs
energy. According to standard thermodynamic phase equilibrium criteria, the
chemical potential of each component must be the same in every phase at equilibrium
where, μi1 is the chemical potential of component A in phase 1 and k is the number of coexisting phases for multiphase multicomponent equlibria.
Based on the above equations, the equilibrium condition may be calculated either
by direct minimization of the Gibbs energy or by using the principle of
equality of chemical potentials (Walas, 1985). The chemical
potential can be expressed in terms of the fugacity of a component by the following
where μ0 is the chemical potential at reference state, T is the temperature, R is the universal gas constant, P0 is the pressure at the reference state and f (p) is the fugacity as a function of pressure. Combination of Eq. 1 and 2 results in the equality of fugacities for the thermodynamic equilibrium under consideration:
where, f is the fugacity of component A or B in phase 1 or 2.
The fugacity approach as proposed by Klauda and Sandler
(2000) has been used to model the hydrate in equilibrium. Their approach
is basically based on solving the condition of equal fugacities of water in
the hydrate phase and the fluid phases as shown in Eq. 4.
The thermodynamic modeled has been developed in commercial available hydrate
software, CSMGem. Ballard and Sloan (2004) have reported
the schematic of development procedure for the selected hydrate program. It
has been proven that the hydrate formation temperatures and pressures for uninhibited
systems are predicted quite well by CSMGem as compared with four other commercial
hydrate programs; CSMHyd, DBRHydrate, Multiflash and PVTsim (Ballard
and Sloan, 2002).
The present study shows the gas hydrate boundary conditions for natural gas components with different compositions, pressure:
and temperature conditions. To verify the accuracy of the model, absolute deviation (AAD%) has been calculated by comparing the predicted data with available literature data for single component systems such as methane, ethane, propane, carbon dioxide and nitrogen with water. Then, similar evaluations are carried out for binary gas systems with water.
RESULTS AND DISCUSSION
Equilibria of pure hydrate formers: A few single components in natural gas were selected to predict the hydrate phase equilibria when they are in contact with water. Hydrate equilibrium data for single gas hydrates such as methane, ethane and propane will become a basis for further understanding if phase equlibria of water with binary hydrate former systems. Figure 1 and 2 show the predicted three phase equilibria (hydrate-liquid water-vapor), H-Lw-V for pure component systems; CH4 and CO2 with available measurement data. As shown in the figures, pressure increases steeply with increasing temperature. Methane hydrate system yield a good agreement with available literature data but the hydrate equilibrium curves for CO2 hydrate is slightly fluctuating with literature data. Technically, methane with small size of molecules forms sI hydrate whereas intermediate size of carbon dioxide allows its molecules to occupy the large cavity (51262) of sI hydrate.
Table 1 shows the absolute average deviation (AAD%) for five different pure components that have been studied in this work. All the hydrate formers have less than 5% of AAD and it can conclude that the pressure prediction for pure components using CSMGem gives good agreement with the available literature data. A maximum deviation of 4% is obtained by propane as a hydrate former and followed by carbon dioxide. Such a graphical comparison of data and deviation calculation for single-component hydrate formers gave reassurance that the prediction for hydrate equilibrium are acceptable in order to proceed to binary and multicomponent predictions.
Figure 3 shows the predicted hydrate equilibrium data for
five different pure components in natural gas. The hydrate equilibrium lines
of all components in natural gas have been compared since the work is on the
separation of CO2 from natural gas.
||Three phase (H-Lw-V) equilibrium line for methane hydrate
||Three phase (H-Lw-V) equilibrium line for carbon dioxide hydrate
It been clearly observed that nitrogen tends to form a hydrate at higher pressure
than the other four components at same temperature.
Due to differences in the volume and enthalpy of the vapour and liquid hydrocarbon,
the three-phase hydrate formation line for ethane, propane and carbon dioxide
change from H-Lw-V to H-Lw-LHC (LHC
is liquid hydrocarbon). For each pure hydrate former, the predictions were bounded
by the ice point (273 K) and the upper quadruple point (H-Lw-LHC-V).
Quadruple point is noted by the phases that are in equilibrium. Basically the
lower quadruple point (Q1) is approximately where the hydrate line
intercepts the melting curve of pure water. Thus, all single hydrate formers
have Q1 approximately at 0°C (273 K). While the upper quadruple
point (Q2) is an interception within the hydrate line and the vapour
pressure curve of the pure hydrate former.
||Predicted hydrate equilibrium of single components in natural
||Absolute deviation (AAD%) results between the experimental
data and predicted data for single hydrate systems
Neither nitrogen nor methane has an upper quadruple since they have lower critical
points which are far below the Q1. Such low critical temperatures
prevent intersection of the vapour pressure line with H-Lw-V line
above 273 K to produce an upper quadruple point. Methane and carbon dioxide
hydrates have been compared in detail since methane is the main component in
the natural gas. It can clearly been observed that carbon dioxide favor to form
hydrate than that methane in the region T = 273.2 to 283.3 K and P = 1.2 to
7.4 Mpa. But the hydrate phase will start richer with methane above this region
due to the sudden changes of hydrate equilibrium line of carbon dioxide hydrate
from the upper quadruple point.
Equilibria of binary guest mixtures: Similar evaluations have been carried out for binary gas systems with water. Table 2 shows the outcomes of absolute deviation (AAD%) for binary mixtures of methane with ethane, propane, carbon dioxide and nitrogen.
Table 2 has shown that all the predicted data are in accordance with previously published work. In general, according to the Gibbs phase rule, for a ternary system (included water) which consisting of two gases + water, the three-phase equilibrium has two degrees of freedom. Thus, a second intensive variable need to be defined as an addition of temperature for equilibrium pressure prediction. The overall composition of the feed stream has been well defined for this case. There are a decrease of hydrate pressure in the mixtures of methane with ethane and propane as compared with pure methane hydrate. These phenomena happen due to the changing of hydrate structure which is from sI to sII. In contrast, the hydrate equilibrium pressure increases as concentration of nitrogen in methane+nitrogen system increase. As been discussed before, nitrogen molecules itself will form hydrate at higher pressure as compared with the other components. Thus, the presence of nitrogen in the mixture will increase the hydrate pressure until it reaches the pure nitrogen hydrate equilibrium line as the concentration of nitrogen in the system increase.
Basically it is not easy to generalize which hydrate structure will be present
when sI and sII hydrate formers are in a mixture. In pure water, methane forms
sI hydrate with its molecules occupying the small cavities (512).
Since the molecular diameter of methane (4.4 Å) is smaller than the free
diameters (~ 5.76 Å) of most cavities in the hydrate lattice, methane
molecules can migrate in the hydrate lattice. Methane molecules will occupy
the small cage in sII hydrate when there is the larger hydrate former present
in the system. Thus, sII hydrate is formed for binary system of CH4-C3H8
since propane molecules cannot enter any of the sI cavities. In this system,
methane will occupy the small cavities while propane molecules occupy the larger
cavities of structure II hydrate. Although methane and ethane form sI hydrates
by themselves, the mixture of these components form sII hydrates at certain
||Absolute deviation (AAD%) results between the experimental
data and predicted data for binary hydrate systems
Subramanian et al. (2000) have reported that
the structure of methane+ethane hydrates changes from sI to sII over a methane
vapor composition range (yCH4) of 0.7360.994 at 274.2 K.
The pressure versus temperature (P-T) diagram for CH4-CO2 mixtures have not been plotted due to inconsistency of CH4 composition in the mixture from the literature data. But still the mixture has less AAD% as compared with the other three mixtures. Since the separation of CO2 from natural gas mixture is the main objective of this work, P-T diagram for CH4 - CO2 system has been plotted using the predicted data (Fig. 4) at different concentration of CO2. The purpose of doing this is to study the effect of CO2 composition in the mixture. Hydrate equilibrium lines for pure CH4 and CO2 hydrates are plotted in the same graph for comparison purpose.
Phase equilibria of CH4-CO2 mixtures were investigated
at temperature between 273.15 and 283.15 K. Mixture of CO2 and CH4
form sI hydrate only, like pure CO2 and CH4 with water
(Uchida et al., 2005). In the mixture of 50%
CH4-50% CO2, the equilibrium line is predicted close to
CO2 hydrate line instead of in the middle of the both single hydrate
formers. Gaudette et al. (1996) have determined
that the distribution coefficient of methane between the gas and hydrate phase
is approximately 2 for mixture of 50/50 CH4 - CO2. Therefore,
CO2 hydrates do indeed form selectively over methane hydrates in
the presence of 50/50 gas mixture. Seo et al. (2000)
reported that the composition of CO2 in the hydrate phase increase
with increasing the CO2 composition in vapor phase and decreasing
the system pressure (Seo et al., 2000). This
selective information will be the basis for utilization of gas hydrate formation
as an approach to separate carbon dioxide from methane.
Equilibria of natural gas with different concentration of carbon dioxide:
Hydrate formation conditions were also been predicted for natural gas mixtures
with and without CO2. Several natural gases containing CO2 from
three gas production fields have been reported by Adisasmito
and Sloan (1992) are listed in Table 3 (Adisasmito
and Sloan, 1992). The pure CO2 was included to indicate the whole
range of concentration.
||Predicted hydrate equilibrium data for CO2-CH4
|| Five different concentration of natural gas components
The hydrate phase equilibria for natural gas system with overall carbon dioxide
concentration of 31.4, 66.85, 83.15 and 89.62 mol% are depicted in Fig.
5. The temperatures have been further extended to predict the hydrate formation
pressure since the temperature in literature is limited to 282 K. From the graph,
it can be clearly observed that the equilibrium curve shift towards higher pressures
as concentration of carbon dioxide in natural gas increase. The concentration
of carbon dioxide in the system is obviously affecting the hydrate formation
condition. The result obtained with the natural gases show the expected dependence
of gas composition on the equilibrium conditions.
The hydrate equilibrium line rises vertically from the upper quadruple point
(Q2), with very large pressure changes for small temperature changes
for each gas except gas A. Hydrate equilibrium line for gas A almost identical
with that pure methane since the gas is mainly consist of methane. Structure
II hydrates are formed in gas A, B and C which the small cavities are occupied
by methane while the large cavities are mostly occupied by the other large components
such as propane, isobutane and butane. In the mixtures have high concentration
of CO2 like gas D and E, structure I hydrates are formed where small
cavities are occupied by methane. While the large cavities of structure I are
being occupied by methane, ethane and carbon dioxide.
|| Hydrate equilibrium data of natural gas with different concentration
of carbon dioxide
In this condition, the very large molecules such as propane, butane and isobutane
will act as gas diluents and do not participate in the structure I hydrate (Gaudette,
et al., 1996). Therefore, both gases required higher pressure for
structure I formation.
In this study, the thermodynamics model has been successful used to predict the phase equilibrium data for single, binary and multi components hydrate former systems. The predicted data of the model has been compared with experimental data for single hydrate former systems including CH4, CO2 systems and the calculated AAD% is less than 5% for three phase equilibrium condition namely H-LW-V. The model is successful used to predict the mentioned equilibrium condition for binary and multi-component hydrate formers system. From this phase behavior data, the region where the hydrate formation can be used as separation process for CO2 from natural gas can be identified.
The authors are thankful to Universiti Teknologi PETRONAS for providing grant and facilities for the research purpose.
Adisasmito, S. and E.D. Sloan, 1992. Hydrates of hydrocarbon gases containing carbon dioxide. J. Chem. Eng. Data., 37: 343-349.
Adisasmito, S., R.J. Frank and E.D. Sloan Jr., 1991. Hydrates of carbon dioxide and methane mixtures. J. Chem. Eng. Data, 36: 68-71.
CrossRef | Direct Link |
Avlonitis, D., 1988. Multiphase equilibria in oil-water hydrate forming systems. M.Sc. Thesis, Heriot-Watt University, Edinburgh, Scotland.
Ballard, A.L. and E.D. Sloan Jr., 2002. The next generation of hydrate prediction: An overview. J. Supramol. Chem., 2: 385-392.
Ballard, A.L. and E.D. Sloan Jr., 2004. The next generation of hydrate prediction IV: A comparison of available hydrate prediction programs. Fluid Phase Equilibria, 216: 257-270.
Carrol, J., 2003. Natural gas hydrates-A guide for engineers. Gulf Professional Publishing, Imprint Amsterdam.
Deaton, W.M. and E.M. Frost Jr., 1946. Gas hydrates and their relation to their operation of natural gas pipelines. Underground Storage. United States Department of the Interior-Bureau of Mines.http://www.prci.com/publicationsnew/L41020.cfm.
Fan, S.S. and T.M. Guo, 1999. Hydrate formation of CO2-Rich binary and quaternary gas mixtures in aqueous sodium chloride solution. J. Chem. Eng. Data, 44: 829-832.
Galloway, T.J., W. Ruska, P.S. Chappelear and R. Kobayashi, 1970. Experimental measurements of hydrate numbers for methane and ethane and comparison with theoretical values. Ind. Enq. Chem. Fundam., 9: 237-243.
Gaudette, J., S. Al-Adel and P. Servio, 1996. Phase equilibria for the CO2-CH4 mixed hydrate system. http://ppeppd07.chemeng.ntua.gr/manuscripts/51.pdf.
Holder, G.D. and G.C. Grigoriou, 1980. Hydrate dissocation pressure of (methane + ethane + water) existence of a locus of a minimum pressures. J. Chem. Thermodyn., 12: 1093-1104.
Holder, G.D. and J.H. Hand, 1982. Multiphase equilibria in hydrates from methane, ethane, propane, and water mixtures. AIChE J., 28: 440-447.
Holder, G.D., S.P. Zetts and N. Pradhan, 1988. Phase behavior in systems containing clathrate hydrates. Rev. Chem. Eng., 5: 1-70.
Jager, M.D. and E.D. Sloan, 2001. The effect of pressure on methane hydration in pure water and sodium chloride solutions. Fluid Phase Equilibria, 185: 89-99.
Jhaveri, J. and D.B. Robinson, 1965. Hydrates in the methane-nitrogen system. Can. J. Chem. Eng., 43: 75-78.
Kang, S.P. and H. Lee, 2000. Recovery of CO2 from flue gas using gas hydrate: Thermodynamic verification through phase equilibrium measurements. Environ. Sci. Technol., 34: 4397-4400.
CrossRef | Direct Link |
Klauda, J.B. and S.I. Sandler, 2000. A fugacity model for gas hydrate phase equilibria. Ind. Eng. Chem. Res., 39: 3377-3386.
Kubota, H., K. Shimizu, Y. Tanaka and T. Makita, 1984. Thermodynamic properties of R13 (CCIF3), R23 (CHF3), R152a (C2H4F2), and propane hydrates for desalination of sea water. J. Chem. Eng. Japan, 17: 423-429.
Marshall, D.R., S. Saito and R. Kobayashi, 1964. Hydrates at high pressures: Part I. Methane-water, argon-water, and nitrogen-water systems. AIChE J., 10: 202-205.
Mei, D.H., J. Liao, J.T. Yang and T.M. Guo, 1996. Experimental and modelling studies on the hydrate formation of a CH4+N2 gas mixture in the presence of aqueous electrolyte solution. Ind. Eng. Chem. Res., 35: 4342-4347.
Miller, B. and E.R. Strong, Jr, 1946. Hydrate storage of natural gas. Am. Gas Assoc. Monthly, 28: 63-67.
Mohammadi, A.H., B. Tohidi and R.W. Burgass, 2003. Equilibrium data and thermodynamics modelling of nitrogen, oxygen and air clathrate hydrates. J. Chem. Data, 48: 612-616.
Mokhatab, S., W.A. Poe and J.G. Speight, 2006. Handbook of Natural Gas Transmission and Processing. Chapter 1, Elsevier Inc., USA., ISBN-10: 0-7506-7776-7, pp: 672.
Mooijer-van den Heuvel, M.M., R., Witteman and C.J. Peters, 2001. Phase behaviour of gas hydrates of carbon dioxide in the presence of tetrahydropyran, cyclobutanone, cyclohexane and methylcyclohexane. Fluid Phase Equilibria, 182: 97-110.
CrossRef | Direct Link |
Nixdorf, J. and L.R. Oellrich, 1997. Experimental determination of hydrate equilibrium conditions for pure gases, binary and ternary mixtures and natural gases. Fluid Phase Equilibria, 139: 325-333.
Reamer, H.H., F.T. Selleck and B.H. Sage, 1952. Some properties of mixed paraffinic and olefinic hydrates. AIME, 195: 197-205.
Direct Link |
Robinson, D.B. and B.R. Mehta, 1971. Hydrates in the propane-carbon dioxide-water system. J. Can. Pet. Tech., 10: 33-35.
Ruffine, L. and J.P.M. Trusler, 2010. Phase behaviour of mixed-gas hydrate systems containing carbon dioxide. J. Chem. Thermodyn., 42: 605-611.
Sabil, K.M., G.J. Witkamp and C.J. Peters, 2010. Estimations of enthalpies of dissociation of simple and mixed carbon dioxide hydrates from phase equilibrium data. Fluid Phase Equilibria, 290: 109-114.
Sabil, K.M., G.J. Witkamp and C.J. Peters, 2010. Phase equilibria in ternary (carbon dioxide + tetrahydrofuran + water) system in hydrate-forming region: Effects of carbon dioxide concentration and the occurrence of pseudo-retrograde hydrate phenomenon. J. Chem. Thermodyn., 42: 8-16.
Scholz, W., G. Ranke, H. Becker, B.G. Bergo, A.I Grienko and A.V. Frolov, 1981. Method of Treating Natural Gas to Obtain a Methane Rich Fuel Gas. Vol. 4, US Patent Publication, USA., pp: 305-733.
Seo, Y.T., S.P. Kang, H. Lee, C.S. Lee and W.M. Sung, 2000. Hydrate phase equilibria for gas mixtures containing carbon dioxide: A proof-of-concept to carbon dioxide recovery from multicomponent gas stream. Korean J. Chem. Eng., 17: 659-667.
Servio, P. and P. Englezos, 2001. Effect of temperature and pressure on the solubility of carbon dioxide in water in the presence of gas hydrate. Fluid Phase Equilibria, 190: 127-134.
Servio, P. and P. Englezos, 2002. Measurement of dissolved methane in water equilibrium with its hydrate. J. Chem. Eng. Data, 47: 87-90.
Sloan, E.D. and C.A. Koh, 2008. Clathrate Hydrates of Natural Gases. 3rd Edn., CRC Press, Boca Raton.
Subramanian, S., A.L. Ballard, R.A. Kini, S.F. Dec and E.D. Sloan, 2000. Structural transitions in methane + ethane gas hydrates-Part I: Upper transition point and applications. Chem. Eng. Sci., 55: 5763-5771.
Thrasher, J. and A.J. Fleet, 1995. Predicting the Risk of Carbon Dioxide Pollution in Petroleum Reservoirs. In: Organic Geochemistry: Developments and Applications to Energy, Climate, Environment and Human History, Grimalt, J.O. and C. Dorronsoro (Eds.). AIGOA, San Sebastian, pp: 1086-1088.
Uchida, T., I.K. Ikeda, S. Takeya, Y. Kamata and R. Ohmura et al., 2005. Kinetics and stability of CH4-CO2 mixed gas hydrates during formation and Long-Term storage. ChemPhysChem, 6: 646-654.
Van Cleeff, A. and G.A.M. Diepen, 1960. Gas hydrates of nitrogen and oxygen. Rec. Trav. Chim., 79: 582-586.
Van der Waals, J.H. and J.C. Platteuw, 1959. Clathrate solutions. Adv. Chem. Phys., 2: 1-57.
Verma, V.K., J.H. Hand and D.L. Katz, 1975. Gas Hydrates from Liquid Hydrocarbons Methane-Propane-Water System. AIChe-VTG Joint Meeting, Munich, pp: 106.
Walas, S.M., 1985. Phase Equilibria in Chemical Engineering. Butterworth-Heinemann, Oxford,ISBN: 978-0750693134.
Wendland, M., H. Hasse and G. Maurer, 1999. Experimental pressure-temperature data on three-and four-phase equilibria of fluid hydrate, and ice phase in the system carbon dioxide-water. J. Chem. Data, 44: 901-906.
CrossRef | Direct Link |
Xiao, Y., B.T. Low, S.S. Hosseini, T.S. Chung and D.R. Paul, 2009. The strategies of molecular architecture and modification of polymide-based membranes for CO2 removal from natural gas: A review. Progress Polymer Sci., 34: 5561-5580.
Zhu, T., B.P. McGrail, A.S. Kulkarni, M.D. White, H. Phale and D. Ogbe, 2005. Development of a thermodynamic model and reservoir simulator for the CH4, CO2 and CH4-CO2gas hydrate system. SPE Western Regional Meeting, March 30-April 01, 2005, Irvine, California, SPE 93976.
Zulkifli, A.M., Y. Zulkefli, M. Rahmat and A.K. Yasmin, 2002. Managing our environmental through the use of clean fuel. Gas Technology Centre (GASTEG), Faculty of Chemical Engineering and Natural Resources Engineering, Universiti Teknologi Malaysia, Malaysia.