Advanced Spaceborne Thermal Emission and Reflection Radiometer Mineral Mapping to Discriminate High Sulfidation, Reduced Intrusion Related and Iron Oxide Gold Deposits, Eastern Iran
Thirty scenes of Aster data from eastern Iran were processed
using the Multispectral supervised classification method for identifying
hydrothermal alteration zones related to possible mineral deposits. Several
areas having great potential for mineral exploration were identified.
ASTER mineral mapping from three known types of gold mineralization in
eastern Iran were compared. Chah Shaljami, a high sulfidation Au (lithocap
of porphyry Cu) prospect, shows alunite, silica, jarosite, dickite, montmorillonite
and gypsum. Alteration is intense and covers an area of 3x4 km2.
Aeromagnetic data show low magnetism within the area of alteration, indicating
that magnetite was destroyed during alteration. Qaleh Zari is a specularite-rich
Iron oxide Cu-Au deposit (IOCG). ASTER mineral mapping shows only epidote
and chlorite. Alteration is narrow and is linear. Aeromagnetic data show
high magnetism in most of the area, therefore alteration did not destroy
the primary magnetite. Hired is a reduced-intrusion-related Au prospecting
area. ASTER mineral mapping shows tourmaline, chlorite, silica and minor
sericite. Alteration is local and is not as extensive as at Chah Shaljami.
Aeromagnetic data show a very broad area of low magnetism that is associated
with reduced ilmenite series intrusive rock.
Aster and Landsat are two important commercial satellites that were launched
to study by remote sensing different aspect of the earth surface, especially
mineral resources. The Advanced Spaceborne Thermal Emission and Reflection Radiometer
(ASTER) is an advanced multispectral imager that was launched on board NASAs
Terra spacecraft in December, 1999 (Abrams and Hook, 2000).
Landsat-1 was launched in 1972 and the most recent, Landsat-7 ETM+,
was launched in 1999.
A remote sensing system has several components, including the sun as
the source of electromagnetic radiation, the transmission path of this
radiation, the target and the sensor. These components work together to
provide information about a target without actually coming into physical
contact with it. To study different aspect of the earths surface, the
satellite sensor must provide the spatial, spectral and temporal resolution
necessary to meet the needs of the application. Spatial resolution refers
to the amount of detail that can be detected by a sensor. ASTER has greater
spatial resolution than Landsat. The spatial resolution of ASTER varies
with wavelength: 15 m in the visible and near-infrared (VNIR), 30 m in
the short wave infrared (SWIR) and 90 m in the thermal infrared (TIR).
Spectral resolution refers to the width or range of each spectral band
measured by a sensor. ASTER covers a wide spectral region with 14 bands
from the visible to the thermal infrared, each with high spatial, spectral
and radiometric resolution.
Spectra of common alteration minerals related to hydrothermal ore deposits
such as alunite, sericite, kaolinite and dickite have several pikes for
wave length of 2.1-2.4 (μm). For wave-lengths of 2.1-2.4 (μm)
Landsat has only one spectral band, but ASTER has five spectral bands.
Therefore ASTER remains far in advance of LANDSAT for differentiating
and to identify these minerals. Each ASTER scene covers an area of 60x60
km. Mineral Mapping these and other minerals with ASTER data it is possible
to identify important and key minerals associated with specific geologic
units and hydrothermal alteration associated with ore deposits.
ASTER mineral mapping is being done for mineral exploration and mapping geological
|| Gold classification
Selective articles in this field are: Mapping hydrothermally altered
rocks at Cuprite, Nevada (Rowan et al., 2003);
Application of ASTER data to geological studies (Rowan and
Mars, 2003; Yamaguchi et al., 1996); Alteration
mineral mapping in the Central Andes (Hubbard et al.,
2007); Mapping lithological variations with visible to thermal infrared
spectroscopy; a case study from Gold Butte (Hook and Howard,
2001); Alteration mineralogy at the Cerro La Mina epithermal prospect, Patagonia,
Argentina (Ducart et al., 2006); Geologic mapping
and mineral resource assessment of the Healy and Talkeetna Mountains Quadrangles,
Alaska. Regional mapping of phyllic- and argillic-altered rocks in the Zagros
magmatic arc, Iran (Mars and Rowan, 2006); Targeting
key alteration minerals in epithermal deposits in Patagonia, Argentina, using
ASTER imagery and principal component analysis (Crosta et
al., 2003); Extraction of promising mineral area and acquisition of
mining property using satellite image analysis technique in northern Chile (Yoshizawa et al., 2003); Copper explorations based on a satellite-image analysis
technique in northern Chile; the recent results of exploration activity (Asaki et al., 2004).
ASTER mineral mapping will be used to discriminate three types of gold deposits
such as high sulfidation Au; Iron Oxide Cu-Au Deposits and Reduced intrusion
related. Gold deposits classified as in Table 1: 1-Porphyry
gold deposits (Hollister, 1992; Stephens
et al., 2004; Sillitoe and Thompson, 1998;
Sillitoe, 1997), 2-Reduced intrusion related (Lange
and Baker, 2001; Sillitoe, 2002); 3-Iron-oxides Cu-Au
(IOCG) (Williams et al., 2005; Sillitoe,
2003; Barton, 2001; Haynes, 2000;
Hitzman, 2000) and 4-Epithermal deposits (Hedenquist
et al., 2000; Sillitoe, 1993). 5-Shear zones
regional metamorphism (Groves et al., 2003).
MATERIALS AND METHODS
Thirty scenes (each is 60x60 km) of Aster data from Eastern Iran were
processed for mineral mapping. Geometric Corrections carried out by ENVI
4.2 software to put ASTER image elements in their proper planimetric (x
and y) positions. To do so more than 50 points in each ASTER image are
registered to corresponding points in digitized topography map (topography
maps at scale of 1:100000 and 1:25000). Radiometric corrections, which
attempt to remove the effects of sensor errors and/or environmental factors.
IAR calibration tools present in ENVI 4.2 software was used to remove
solar irradiance, atmospheric transmittance, instrument gain, topographic
effects and albedo effects from radiance data.
Different methods are being used for mineral mapping such as: 1-principal
component analysis (PCA); 2-Ratio Images (Ratio images are prepared by
dividing the DN in one band by the corresponding DN in another band for
each pixel, stretching the resulting value and plotting the new values
as an image). Ratio of bands 4/6 identifies all types of clay, 7/6 alunite,
pyrophyllite, 8/6 alunite, 9/8 calcite, talc, chlorite and epidote. 3-Multispectral
Classification (Supervised Classification, Unsupervised Classification,
Minimum Distance Classification, Maximum Likelihood Classification, Probabilistic
Neural Network Classifier).
The multispectral supervised classification method was used in this research
and exploration. Processing procedures were done by ENVI 4.2 software using
Multispectral supervised classification method (Sabins, 1999).
To establish a GIS database, important information such as geology, mining and
geophysics were digitized:
||22 Geological maps at scale of 1:100000 from eastern
Iran were digitized.
||Active-abandon mine and mineral index were digitized
||Aeromagnetic, U-Th data (specially taken for mineral exploration)
were obtained from Geological Survey of Iran.
The results of ATER Mineral mapping were checked on the ground to verify
the result of image processing.
RESULTS AND DISCUSSION
Geology and mineralization: Three contrasting type of gold deposits
were studied, including: 1-Iron Oxides Cu-Au (Qaleh Zari deposit); 2-Reduced
intrusion related Au (Hired) and 3-High Sulfidation lithocap porphyry
copper (Chah Shaljami). They are located within the Lut Block in Eastern
Iran (Fig. 1).
||Schematic map of the location of Hired, Qaleh Zari and
Chah Shaljami within the Lut Block
The Lut Block is essentially a north-south-trending
microplate surrounded by the mountain ranges of central and eastern Iran
(Fig. 1). The Lut Block extends over 900 km in a north-south
direction and is only 200 km wide in an east-west direction. It is confined
by the Nayband fault and Shotori Range in the west and the Eastern Iranian
Ranges in the east (Fig. 1). The western edge of the
Lut Block is cut off by the Nayband normal fault. The northern termination
of Lut Block is the depression of Kavir-e-Namak and the Great Kavir Fault.
The Bazman volcanic complex and the Jaz-Murian-Depression define the southern
edge. The eastern edge is dissected by Sistan suture zone (Fig.
1). The Lut Massif has a relatively low degree of Cretaceous Alpine
deformation. Most of the area is covered with Tertiary volcanic and plutonic
rocks, continental sediments and scattered outcrops of Mesozoic and Paleozoic
Qaleh Zari deposit: Qaleh Zari is specularite-rich Cu-Au deposit (IOCG).
The oldest rocks exposed in the mine area are Jurassic shale and sandstone (Fig.
2). Tertiary volcanic rocks are dominant in the mine area and in the region
(Karimpour et al., 2005). They consist mainly
of K-rich andesite and andesitic-basalts, with minor dacite and basalt.
||Geological map of Qaleh-Zari area
Fe of the volcanic rocks in the Qaleh-Zari region is high (TFeO = 6 to 8.4%)
and most of Fe is present as Fe2O3 (Fe2O3 = 2.2 to 5.34%) (Karimpour et al., 2005). These
volcanic rocks are calc-alkaline to K-rich calc-alkaline with transition to
shoshonitic association. They have a geochemical signature typical of subduction-related
Three main mineralized zones were identified in the area. The NW part
of the deposit (No. 1), which is associated with three major sub-parallel
quartz veins, the SE portion (No. 3) and the central part (the main vein
Quartz is the most common constituent in all of the veins, forming euhedral
crystals, 1 to 10 cm long and the quartz veins and veinlets typically have specularite
(hematite) bands at the margins (Fig. 3). Specularite makes
up 10 to 25% of the veins and is the most abundant oxide after quartz.
veins and veinlets, the general paragenetic sequence was: specularite followed
by quartz-chlorite associations and finally chalcopyrite (Fig.
3). Different sulfosalts characterize each stage of the mineralization (Karimpour et al., 2005). The ore grade ranges between 2 to 9 wt. % Cu, 100
to 650 ppm Ag and 0.5 to 35 ppm Au.
Propylitic alteration assemblages are very widespread in the Qaleh-Zari area.
Epidote and chlorite are the two characteristic minerals of this assemblage.
Epidote is very abundant and formed by alteration of plagioclase, pyroxene and
hornblende. Epidote is also abundant as veinlets filling the joints. Chlorite
formed by alteration of mafic minerals or directly from the ore fluid within
the vein (Fig. 2). Chlorites are generally Fe-rich types such
as ripidolite with minor bronsvigite and pycnochlorite (Karimpour
et al., 2005). Argillic alteration is locally present. Silicification
is mainly found within a zone adjacent to the veins.
Chah Shaljami is high sulfidation Au prospecting area (lithocap of porphyry
Cu-Au). It is located about 20 km south of Qaleh Zari (Fig.
1). Andesite to andesite basalt is the main rock exposed in this area.
Monzonite to quartz monzonite dikes and small stocks intruded the volcanic
rocks. Sub-volcanic rocks are part of a bigger stock at depth. Alteration
is very broad and covers an area 2x3 km.
Hired is reduced intrusion related Au prospecting area. It is located
about 75 km north east of Qaleh Zari mine (Fig. 1).
The oldest rocks exposed in the study area are Jurassic shale and sandstone
(Fig. 4). Cretaceous rocks are conglomerate, sandstone,
limestone and tuff.
Magmatic activities during Paleocene-Eocene were mainly andesite in composition
(Fig. 4). Two series of granitoids (magnetite and ilmenite-series)
were identified in the study area (Fig. 4) (Karimpour
et al., 2008). Magnetite suites are exposed in northeast of the study
area (Fig. 4). The magnetite suites consist of at least four
types of intrusive: gabbro, biotite-hornblende diorite, biotite-hornblende monzodiorite
and biotite-hornblende quartz monzonite. The ilmenite suites are exposed in
central and some in western portion of the map. Several intrusive rocks belong
to the ilmenite series are identified. Four of them are shown on the map. These
are granite, biotite granite, biotite-hornblende quartz monzonite and hornblende
diorite (Fig. 4).
Four style of mineralization such as stockwork, skarn, vein and replacement
were identified (Karimpour et al., 2008). Stockwork
mineralization is present within and near the ilmenite series granite porphyry
(Fig. 5). It has exposure in the central part of the map Target
No-I (Fig. 4). Stockwork consists of different veinlets such
tourmaline, quartz, quartz-sulfides, quartz-calcite and quartz-chlorite. The
width of veinlets varies between 1-20 mm. Mineral paragenesis of the stockwork
is plotted in Fig. 6. Quartz, tourmaline, arsenopyrite, pyrrhotite,
galena, sphalerite ± chalcopyrite are the main mineral.
Four types of alteration are identified: propylitic, tourmaline-sericite,
chlorite-tourmaline, tourmaline- sericite-quartz. Propylitic dominate
and cover large area.
It consists of chlorite and minor calcite. Tourmaline-sericite-quartz
alteration is found with stockwork mineralization (Fig.
ASTER mineral mapping and aeromagnetic: The type of minerals formed
due to alteration is mainly control by chemical composition of the hydrothermal
fluid. The size and geometry of alteration halos directly related to the
volume of hydrothermal fluid. Porphyry Cu are big deposits, therefore
their alteration halos are more than several km2.
|| ASTER Mineral mapping show alunite and jarosite
In order to be able to produce a good ASTER mineral mapping and to be
able to identify the type of a deposit before going to the field it is
important to know: 1-Petrochemistry and petrogenesis of igneous rocks
is the fundamental key for understanding how and where igneous related
ore deposits were formed. For instance, porphyry Cu, Sn, Mo and W is associated
with intrusive rocks with special petrogenesis and tectonic setting. Porphyry
Cu deposits are related to intermediate, calc-alkaline sub-volcanic formed
in subduction setting. 2-Geochemistry of hydrothermal ore deposits with
respect to alteration and the role of complexes in carrying the metals
and how and where they precipitate; 3-Alteration patterns formed in each
deposits and 4-knowledge and experiences with remote sensing and mineral
More than 50 areas having potential for mineral exploration were identified.
Amount them three areas chosen for this article. We combined ASTER mineral
mapping result with the aeromagnetic data. It turned out that it is possible
to identify and discriminate between different deposits. In this article,
three types of gold deposits were compared: 1-High-sulfidation (lithocap
of porphyry Cu-Au); 2-Iron oxides Cu-Au (IOCG) and 3-Reduced intrusion
related Au deposit.
Chah Shaljami and Qaleh Zari: ASTAR mineral mapping for Qaleh
Zari and Chah Shaljami areas are shown in Fig. 7-11.
Only chlorite, zoisite and epidote are common in both areas (Fig.
10-11). At Qaleh Zari, epidote is very abundant
(Fig. 11). At Chah Shaljami two types of chlorites
are mapped (Fig. 11). Alunite, silica, dickite, montmorillonite,
gypsum, hematite, jarosite are mapped only at Chah Shaljami area (Fig.
7-10). Chlorite and epidote at Qaleh Zari show
a linear trend NW-SE (Fig. 11). This indicates that
the mineralization is vein type, which has been documented based on the
filed work. Mineral mapping shows that alteration within Chah Shaljami
area was very intensive and covers a large area. Alteration shows good
zoning at Chah Shaljami. A chlorite-epidote propylitic zone surrounds
other minerals. One area at Chah Shaljami is about 3x4 km2
(Fig. 7). Based on these data, the chemistry of the
hydrothermal fluid was totally difference between Qaleh Zari deposit and
Chah Shaljami Au-Cu prospecting area. At Chah Shaljami, the following
minerals are the signs of high sulfidation: Alunite, silica, jarosite,
dickite, montmorillonite and gypsum. The geometry of the alteration and
strong alteration is important sign that this high sulfidation is lithocap
of a porphyry Cu mineralized system.
|| ASTER Mineral mapping show dickite and montmorillonite
|| ASTER Mineral mapping show silicified areas and secondary
|| ASTER Mineral mapping show zoisite and gypsum
|| ASTER Mineral mapping show Epidote and two types of
|| Aeromagnetic, RTP map
Aeromagnetic data show very low magnetism at Chah Shaljami (Fig.
12). This is a porphyry Cu system and the source rocks were magnetite
series granitoids. Due to strong alteration magnetite was destroyed. High
magnetism is present within the epidote-chlorite propylitic zone. At Chah
Shaljami, low magnetism covers large area (Fig. 12).
This corresponds well with ASTER mineral mapping. U (cps) is very high
at Chah Shaljami (Fig. 13).
Hired; Doing ASTER mineral mapping, tourmaline, chlorite, silica, calcite
and minor sericite are mapped at Hired (Fig. 14, 15).
Alteration is local and their mineral assemblages are different from Qaleh
Zari and Chah Shaljami. In comparison with Qaleh Zari it has tourmaline,
silicification and minor sericite. At Qaleh Zari, epidote is very important.
Chlorite at Qaleh Zari is Fe-rich and at Hired they are Mg-rich type.
It has major differences with Chah Shaljami such as absence of alunite,
jarosite, dickite, montmorillonite, gypsum. The size and shape of altered
mineral assemblages is smaller and the intensity is less than Chah Shaljami.
Aeromagnetic data shows very low magnetism at Hired (Fig.
16). This low magnetism is related to reduce intrusive rocks and not
to alteration (Fig. 4). Low magnetism covers large area
but alteration is local (Fig. 16). High magnetism is
associated with oxidant intrusive magnetite-series rocks (Fig.
16). The hydrothermal fluid was associated with the reduced intrusive
rocks. U (cps) is high within area having low magnetism (Fig.
16-17). High U is associated with reduced intrusive
rocks (Fig. 13).
Based on mineral paragnesis and alteration (pH, Log f O2
- Log f S2, chemical composition of hydrothermal ore
bearing solution can be derived). Based on mineral paragnesis and type
of alteration Qaleh Zari, Chah Shaljami and Hired are plotted in Fig.
18. Qaleh Zari Iron oxide Cu-Au deposit (IOCG) is highly oxidant,
low sulfur; pH>7 and the intrusive source was also highly oxidant (based
on hematite, chlorite and epidote) (Table 2). Hired
gold prospecting (Fig. 18) is highly reduced, medium
sulfur, pH 4-7 and the intrusive source was reduced ilmenite series granitoids
and associated elements are Au, Sn, As, Sb, Pb, Zn (based on pyrrhotite,
arsenopyrite, tourmaline, sericite and ilmenite series granitoids) (Table
|| Uranium cps map (Arial data)
|| ASTER Mineral mapping show different minerals
|| ASTER Mineral mapping show different minerals
|| Aeromagnetic, RTP map from Hired
|| Uranium cps map (Arial data) from Hired
|| Log f O2 versus Log f S2
and location of the three types of gold system
|| Special characteristics of the gold deposits
Chah Shaljami is high sulfidation Au (Fig. 18),
highly oxidant, high sulfur, pH< 2 and the intrusive source was oxidant
(based on alunite, dickite, Gypsum and Jarosite) (Table
ASTER mineral mapping is very useful, cheap and fast method of searching
and finding important area for mineral exploration especially in Eastern
Iran where arid conditions have produced good rock exposure. Several areas
having great potential for mineral exploration were identified (Province
of South Khorasan, Eastern Iran). Besides this, It is also possible to
discriminate between different types of deposits. Specularite-rich Iron
oxides Cu-Au deposits show only epidote and Fe-rich chlorite, but no secondary
hematite. High sulfidation Au deposits show alunite, jarosite, dickite,
chlorite, epidote. Reduced intrusive related Au show tourmaline, carbonate,
silica, Mg-rich chlorite and minor sericite.
This article is the result of research grant (p/741-date 22-July-2008)
from Ferdowsi University of Mashhad, Iran.
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