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Research Article
 

Lignin Graft Copolymer as Mud Thinner for Deep Well Drilling Operation



M.N. Mohamad Ibrahim , M.N. Noorhaida , M.Y. Nor Nadiah , M.G. Azilawati and S. Shuib
 
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ABSTRACT

Lignin extracted from black liquor of oil palm Empty Fruit Bunch (EFB) was refluxed with acrylic acid at 30°C in the presence of nitrogen atmosphere to form lignin acrylic acid (lignin AA). Methanol was used as a reaction medium in this experiment. At the end of the copolymerization process, a small amount of hydroquinone 1% was added to inhibit polymerization process. The formation of graft copolymer was proven by the attachment of acrylic acid side chain to the lignin, which was demonstrated by Differential Scanning Calorimetry (DSC) and infrared (IR) spectroscopy analyses. Rheological performances of lignin AA as a drilling mud thinner were compared with a commercial thinner (lignosulfonate). Results found that the newly formulated thinner (lignin AA) shows better thinning performance at high temperature (190°C) with the optimum dosage of 0.3% of total mud volume for water based mud system compared to lignosulfonate. Furthermore, the lignin AA also shows better performance as a fluid loss reducer agent against a commercial fluid loss reducer agent, Ressinex II towards salt contamination.

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  How to cite this article:

M.N. Mohamad Ibrahim , M.N. Noorhaida , M.Y. Nor Nadiah , M.G. Azilawati and S. Shuib , 2006. Lignin Graft Copolymer as Mud Thinner for Deep Well Drilling Operation. Journal of Applied Sciences, 6: 2593-2598.

DOI: 10.3923/jas.2006.2593.2598

URL: https://scialert.net/abstract/?doi=jas.2006.2593.2598

REFERENCES
1:  Alonso, V., A. Martin, R. Borja and A. Chica, 1993. Anaerobic treatment of wastewater produced in the manufacture of cellulosic pulp from wheat straw. Environ. Technol., 14: 1145-1153.
Direct Link  |  

2:  American Petroleum Institute, 1997. Recommended Practice Standard Procedure for Field Testing Water-Based Drilling Fluids. 2nd Edn., American Petroleum Institute, Washington, DC., pp: 5-6.

3:  Bourgoyne, A.T. Jr., K.K. Millheim, M.E. Chenever and F.S. Jr. Young, 1991. Applied Drilling Engineering. Society of Petroleum Engineers, Richardson, Texas, pp: 42-47.

4:  Khoo, K.C. and T.W. Lee, 1991. Pulp and paper from oil palm. Appita, 44: 385-388.

5:  Lubis, A.U., P. Gurito and Darkano, 1994. Prospect of palm oil solid waste based in industries in Indonesia. Proceedings of the 3rd National Seminar on Utilisation of Oil Palm Tree and Other Palms, Sept. 27-29, Kuala Lumpur, pp: 62-84.

6:  Meister, J.J., D.R. Patil and H. Channell, 1985. Synthesis, characterization and testing of lignin graft copolymers for use in drilling mud application. Proceedings of the SPE Oilfield and Geothermal Chemistry Symposium, Mar. 9-11, Phoenix, Arizona, pp: 1-7.

7:  Mohamad-Ibrahim, M.N., M.N. Nazlina, A.D. Fauzana and S.B. Chuah, 2003. Recycling black liquor of oil palm EFB into drilling mud thinner. J. Phys. Sci., 24: 114-115.

8:  Ibrahim, M.N.M., S.B. Chuah and P.Y. Cheng, 2003. Tin-tannin-lignosulfonate complex: An improved lignosulfonate-based drilling fluid thinner. J. Teknologi, 38: 25-32.
Direct Link  |  

9:  Sun, R.C. and J. Tomkinson, 2001. Fraction separation and physico-chemical analysis of lignin from the black liquor of oil palm trunk fibre pulping. Separat. Purificat. Technol., 24: 529-539.
Direct Link  |  

10:  Van Olphen, H., 1963. An Introduction to Clay Colloid Chemistry: For Clay Technologists, Geologists and Soil Scientists. John Wiley and Sons, New York, Pages: 301.

11:  Daud, W.R. and J.L. Valade, 1998. Chemical pulping of oil palm empty fruit bunches. Cell. Chem. Technol., 32: 133-143.

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