Type of Sandstone and Source of Carbonate Cement in the Kongdian Formation (Upper Part), South Slope of the Dongying Depression, East China
Yang Xaing Hua
The Upper part of the Kongdian formation of the Paleocene-Eocene age consists mainly of fine to medium sandstones. Samples analyzed are from depths of 1572.55 to 2298 m, representing a temperature range of 60.5 to 88.5°C. The petrographic analysis reveals that the reservoir of the Upper part of the Kongdian formation consists mainly of feldspathic and minor amounts of lithic arenite sandstones. The feldspathic sandstone belongs to this formation of composite sources: metamorphic, sedimentary and igneous. The majority of the sources of sandstone of the Upper part of the Kongdian formation came from metamorphic rocks. The carbonate cement of the Upper part of the Kongdian formation contains δ 13C with a range of -6.67 to -21.44 with a mean of -14.06 and δ 18O with a range of -1.25 to -12.69 with a mean of -6.97. The δ13C may suggest a mixed source from abiotic reaction zone, bacterial oxidation zone, bacterial sulphate reduction zone and from carbonate detrital grain. The majority of the sources of carbon came from the abiotic reaction zone (decarboxylation zone and liquid hydrocarbon generation zone). The δ 18O values in the carbonate cement of the Upper part of the Kongdian formation reflect a change in temperature and a change in pore waters chemistry.
Isotope is derived from Greek (meaning equal phases) and indicates that isotopes
occupy the same position in the Period Table. Thus isotopes are defined as atoms
whose nuclei contain the same number of protons but different number of neutrons.
The carbon has two stable isotopes 12C and 13C. The heavy
carbonate with δ-value more than +20 and light carbonate with δ-value
of around -90. There are two methods of preparation and the gas used in all
13C/12C measurements is CO2. The first methods
is the one in which carbonates react with 100% phosphoric acid at temperatures
between 25°C and 75°C to liberate CO2.The second method involves
organic compounds generally oxidized at ~1000°C in a stream of oxygen or
CuO. The carbon isotopic composition is conventionally given in parts per thousand
For carbonate, it is convenient to use international reference of Cretaceous
Belemnite for the Pee Dee formation (PDB). The oxygen isotopic composition is
conventionally given in part per thousand in δ-notation:
Two different scale of oxygen, δ18O (SMOW) Standard Mean Ocean Water and δ18O (PDB), the conversion equation of δ18O (PDB) versus δ18O (SMOW):
δ18O SMOW= 1.03086 δ18O PDB+30.86%
And for CO2 samples:
δ18O SMOW= 1.04143 (δ18O PDB- CO2)+30.86%
δ18O SMOW=1.4115 (δ18O SMOW- CO2)+30.86%
The analysis of stable isotopes can provide good information on the cementing
materials in sedimentary rocks. The carbon and oxygen isotopes are applied to
investigate the conditions under which the minerals formed. The stable isotope
is used to distinguish between marine and non-marine pore waters. Carbon and
Oxygen isotopes reflect changes in pore-fluid composition during burial. The
stable isotope is used to identify the source of carbon for carbonate cement[2-11].
The primary aim of this study was to characterize the reservoir of the Upper
part of the Kongdian formation of the Paleocene-Eocene age in terms of sandstone
types, cement types and their sources.
Geological setting: The Bohai Bay Basin belongs to the Eastern region
basins (onshore) and sometime known as the Gulf of Bohai Basin. The Bohai Bay
Basins is located in Northern China on (115° to122° E longitude and
36° to 42° N latitude) and has an area of 200,000 sq km (Fig.
1). Bohai Bay Basin is characterized by its formation in Tertiary age as
part of the Northern China Platform and comprises many depressions (such as
Ba Xian, Raoyang, Jin Xian, Qiu Xian, Dongpu, Banqiao, Dongying, etc.). The
basin contains rocks of the Archean, Proterozoic, Paleozoic, Mesozoic and Cenozoic
periods. The basin was center of major tertiary tectonic activity and controlled
primarily by the movement of the Pacific plate. The hydrocarbons present were
generated during the time of basin formation and migrate over a short distance.
The subsidence of this basin may be fault depressions or down warps. During
the Tertiary period the depositional environment in the basin consisted of continental
life in fresh to brackish water[12-14]. The Cenozoic Strata in the
Bohai Bay Basin are composed of fluvial lacustraine sediments of dark clastic
rocks intercalated with gypsum and halite layers. The Oligocene age was the
main evolution period of the Bohai Bay Basin and consists of fluvial lacustraine
facies. The Neogene strata are composed of fluvial swamp facies.
The Cenozoic strata in the Bohai Bay Basin are divided into: the Kongdian formation
of the Paleocene-Eocene age, the Shahejie formation of the Eocene-Oligocene
age, the Dongying formation of the Oligocene age, the Guantao formation of the
Miocene age and the Minhuazhen formation of the Pliocene age[14-15].
Sedimentology of Kongdian formation: The Kongdian formation is divided into-three parts (Table 1): Lower, Middle and Upper. The Lower part of the Paleocene age is characterized by purple and brown mudstone interbeded with sandstone and conglomerate at the bottom basalt. The Middle part also of the Paleogene age is characterized by fluvial marsh deposits, dark grey and light grey mudstone interbeded with siltstone, carbonate, oil shale, thin coal bed and limestone. The dark mudstone might be the source rock in the basin. The Upper part of the Paleocene-Eocene age is composed of grey, green, brown and white fluvial facies. The fluvial facie is marked by mudstones intercalated with sandstones and siltstones. This study is concerned only with the Upper part of the Kongdian formation of Paleocene-Eocene age.
|| Location map of the study area
|| Sedimentology of the Kongdian formation[14,15]
|Fp= Plagioclase feldspar, Fk = K.feldspar, Qm=Monocrystalline
quartz, Qp= Polycrystalline quartz
|| Percentage of the minerals in the Upper part of the Kongdian
MATERIALS AND METHODS
Twenty-one samples have been selected from the Upper part of the Kongdian formation. The samples represent different depths in this formation. Thin sections were prepared and examined under a polarized microscope (Table 2). Ten samples were taken from the carbonate cement of sandstone of the Upper part of the Kongdian formation. The samples represent different depths in this formation. The whole samples were powdered in a tungsten carbide ball mill and were combined with anhydrous phosphoric acid to produce carbon dioxide gas. Table 3 gives the results of isotopic analysis of carbonate cement of the Upper part of the Kongdian formation.
||δ 13C, δ 18O for carbonate
cement of the Upper part of the Kongdian formation
||Percentage of quartz, feldspar and rock fragment in the Upper
part of the Kongdian formation
Detrital composition of the sandstones: About 400-600 grains were counted
per each slide; and the point counts were recalculated as indicated in Table
4. Over 90% of the samples lie in the field of the feldspathic or sub-feldspathic
arenite sandstones (Fig. 2). The feldspathic arenite sandstone
of the Kongdian formation have a feldspar content of more than 25% and little
rock fragments in their matrix such as, siltstone, mudstone, chert and volcanic
fragments. The sub-feldspathic arenite sandstone contains less feldspar than
feldspathic arenite. The feldspar is chiefly plagioclase feldspar rather than
RESULTS AND DISCUSSION
Classifications of sandstones depend on mineral composition of quartz, feldspar
and lithic fragments. Most of the samples lie in the field of feldspathic and
sub-feldspathic arenite sandstone and minor amount lie in the field of lithic
arenite sandstone (Fig. 2). Among feldspathic sandstones,
which is abundant in quartz, feldspar content of more than 25% and lesser amounts
of lithic fragment, have long been known by term the Arkose which have
granitic or granodioritic composition suggesting derivation from coarsely crystalline
basement. The composition of the feldspathic sandstone contains
less than 25% feldspar, reflecting sub-arkose or sub-feldspathic sandstone.
The detrital grains of perthite, microline and orthoclase usually indicate a
source area where granitic and high-grade gneisses and schists are exposed.
The detrital grains of sandine (K, Na) Al Si3 O8 indicate
alkalic volcanic source, while detrital albite comes chiefly from low-grade
metamorphic terrains. The potassic and sodic feldspar are most
numerous because they are relatively stable and widespread and abundant in continental
source terrains. Lithic sandstones are those, which contain abundant
quartz, more than 25% of lithic grains and lesser amounts of feldspar.
Sub-lithic sandstone contains less than 25% of lithic grains.
The lithic grains may be indicative of the kinds of source rock terrains from
which sand grains were derived, such as small particles of volcanic rock derived
from a volcanic source, chert grains derived from a sedimentary source and mica
which, may be of a igneous or metamorphic source. The feldspathic
arenites, which occur throughout the entire geological column, have obvious
provenance significance; a feldspar-rich source area is characterized by predominant
K-feldspar consisting of granites, gneisses and other high-rank metamorphic
rocks. The feldspathic sandstone (Fig. 3, 4
and 5) in the study area is characterized by: (1) High abundance
of quartz, (2) More than 25% feldspar content, (3) Little rock fragments in
their matrix such as, siltstone, mudstone, chert and volcanic fragments. The
texture of feldspathic sandstone is mainly moderately sorted with rounded grains
and angular ones. All the grains are cemented by a matrix usually contains carbonate
and silt or clay. The sub-feldspathic arenite sandstone contains less feldspar
than feldspathic arenite. The feldspar is chiefly plagioclase feldspar with
lesser amounts of K-feldspar. Quartz is characterized by angular to round grains.
The lithic arenite sandstones are characterized by: abundance quartz, more than
25% lithic grains and lesser amounts of feldspar. The lithic
fragments of sandstones in the study area are characterized by: abundance of
rock fragments, especially that of sedimentary origin and lesser amount of volcanic
|| Classification of sandstone of the upper part of the Kongdian
Feldspathic sandstone. The upper part of the Kongdian formation
at depth 2280.00 m. (Q) quartz, (F) feldspar
Piokilotopic calcite cement. The Upper part of the Kongdian
formation at depth 2228.00 m. (Q) quartz, © calcite
||Plagioclase grain (P), The Upper part of the Kongdian formation
at depth 2224 m
The feldspar in feldspathic and lithic sandstones in the study area is composed
of sodic and potassic feldspar, suggesting derivation from igneous and metamorphic
sources. The lithic fragments in feldspathic and lithic sandstone in the study
area consist of chert and volcanic grains, indicating derivation from volcanic,
metamorphic and sedimentary source areas. Thus feldspathic and lithic arenite
sandstones belonging to the study area indicate the derivations from composite
sources: igneous, metamorphic and sedimentary. Most of the sandstone of the
Upper part of the Kongdian formation came from a metamorphic source.
||Plot of δ 13C versus depth for carbonate
cement of the Upper part of the Kongdian formation
||Plot of δ 18O versus depth for carbonate
cement of the Upper part of the Kongdian formation
The carbonate cement of the Upper part of the Kongdian formation contains δ
13C with a range of -6.67 to -21.44 with a mean of -14.06 and δ
18O with a range of -1.25 to -12.69 with a mean of -6.97. Fig.
6 shows that with increasing depth, the positive shift in δ 1;C
of carbonate cement in the sandstone reflects the positive in δ 13C
of the pore water. Macaulay et al. noted that the carbon
isotopic composition (δ 13C) of diagenetic carbonate minerals
reflects the origin of the carbon from which they are composed. In the rift-setting
sedimentary basin such as the North Sea, many possibilities exist for sources
of carbon from: (1) Marine bicarbonate with δ 13C around 0 .
(2) Dissolved inorganic in meteoric water for δ 13C of total
dissolved carbon (TDC) range from positive to negative and depend on a combination
factors such as (CO2 from organic carbon contains δ 13C
~ -25 , carbon from dissolution of carbonate contains δ 13C
~ +2 and atmospheric CO2 contains δ 13C ~
-7 ). (3) Dissolution shell debris contain δ 13C
values close to 0 . (4) From plant and animals remains contain values
of δ 13C from -20 to -30 . Irwin et al.
proposed a general model for sources of carbon. The model suggests that, with
increases in depth involved: bacterial oxidation, bacterial sulphate reduction,
bacterial fermentation and abiotic reactions produce CO2 (with δ
13C values of -25 , -25 , +15 and -10 to -25 ,
respectively). Also kerogen and petroleum generated from deeper burial contains
δ 13C values of -20 to-30 . The biodegradation of petroleum
may be the source of CO2 with δ 13C values +14 to
-20 and magmatic CO2 with δ 13C values of
~ 7 [1,9]. The association of pyrite with non-ferroan calcite
suggests that sulphate reduction was also contributing bicarbonate to cement[8,16].
The majority of carbonate cement of the Upper part of the Kongdian formation
in the study area has a carbon isotopic ratio more than -11 PDB
and less than -22 PDB. This may suggest a mixed source from
abiotic reaction, bacterial oxidation and bacterial sulphate reduction. But
the majority of the sources of carbon came from the abiotic reaction zone. Curtis
divided the abiotic reaction zone into decarboxylation zone, liquid hydrocarbon
generation zone and gas graphite zone. The decarboxylation zone is characterized
by: (1) Depth ranges from 1 to 2.5 km and temperature of 30 to75°C, (2)
δ 13C values of -20, (3) Minerals precipitated including
ferroan dolomite, kaolinite, smectite, mixed layer clays and illite. The liquid
hydrocarbon generation zone is marked by: (1) Depth of 2.5 to 4.0 km and temperature
ranges from 75°C to 120°C, (2) Carbon from primary or early diagenetic
carbonates, (3) Minerals precipitated including calcite, dolomite, ferroan dolomite,
siderite, kaolinite, smectite, mixed layer clay and illite. The gas graphite
zone is characterized by: (1) Depth of more than 4.5 km and temperature more
than 120°C, (2) Minerals precipitated including calcite, dolomite, ferroan
dolomite, siderite, kaolinite, mica development and chlorite. The less negative
13C values may indicate the contribution of a heavier carbon released
during bacterial fermentation or from the other source. The two most obvious
causes for the positive shift with depth in δ 13C values in
the pore water are the increasing percentage of detrital carbonate in sand stone
and the exclusion of surface water from the closed system of deep sandstone.
Figure 4 shows variation with depth in δ 18O
values of sandstone cement of the Upper part of the Kongdian formation and may
reflect changes in temperature of precipitation and changes in δ 18O
of the pore waters. According to Dickson the variations with depth
in δ 18O values of sandstone cements may reflect changes in
temperature of precipitation and change in δ 18O values of the
pore waters. Figure 7 shows that with increasing in depth,
the negative shift of δ 18O values. The trend of negative shift
of δ 18O values of carbonate cement with increasing in depth
might result from increasing of temperatures. Thus the δ
13C values of carbonate cement in the Upper part of the Kongdian
formation may suggest derivation of CO2 from different source: (1)
Bacterial oxidation, (2) Bacterial sulphate reduction, (3) Bacterial fermentation,
(4) Abiotic reaction zone, (5) From detrital carbonate found in sandstone. But
the majority was derived from the abiotic reaction zone (decarboxylation zone
and liquid hydrocarbon generation zone). The δ 18O values in
carbonate cement of the Upper part of the Kongdian formation reflect change
in temperature and change in pore waters chemistry.
The Upper part of the Kongdian formation of the Paleocene-Eocene age consists mainly of feldspathic sandstones and minor amounts of lithic sandstone. The feldspathic sandstones belong to this formation of composite sources: metamorphic, sedimentary and igneous sources, but mainly from a metamorphic source.
The carbon isotope analysis may suggest that the δ 13C values of carbonate cement in the Upper part of the Kongdian formation derived CO2 from different sources: bacterial oxidation, bacterial sulphate reduction, bacterial fermentation, abiotic reaction zone and from detrital carbonate found in sandstone. But the majority was derived from the abiotic reaction zone (decarboxylation zone and liquid hydrocarbon generation zone). The δ 18O values in carbonate cement of the Upper part of the Kongdian formation reflect change in temperature and change in pore waters chemistry.
I would like to express my appreciation to my friends Stephen Donyinah from Ghana and Neil Kirkland from Canada for revising the final manuscript.
Carozzi, A.V., 1993. Sedimentary Petrography. PTR Prentice, Englewood Cliffs, New Jersey, pp: 17-26.
Curtis, C.D., 1978. Possible links between sandstone diagenesis and depth-related geochemical reactions occurring in enclosing mudstones. J. Geol. Soc. London, 135: 107-117.
Dickson, J.A.D., 1988. Isotopic and petrographic evidence for carbonate diagenesis in non-marine sandstones, Green River basin, Wyoming. J. Sediment Petrol., 58: 227-388.
Hamilton, P.J., A.E. Fallic, R.M. Macintyre and S. Ellitt, 1987. Isotopic Tracing of the Provenance and Diagenesis of Lower Brent Group Sands, North Sea. In: Petroleum Geology of NW Europe, Brooks, J. and K. Glenine (Eds.). Graham and Trotman, London, pp: 939-949.
Hoefs, J., 1987. Staple Isotope Geochemistry. Springer-Verlag, Berlin, Germany, pp: 241.
Hu, J., S. Xu, X. Tong and H. Wu, 1989. The Bohai Bay Basin. In: Chinese Sedimentary Basins, Zhuxia (Ed.). Elsevier, Amsterdam, pp: 89-105.
Hudson, J.D., 1977. Stable isotope and limestone lithification. J. Geo Soc. London, 133: 637-660.
Irwin, H., C.D. Curtis and M.L. Coleman, 1977. Isotope evidence for source of diagenetic carbonates formed during burial of organic-rich sediments. Nat. London, 269: 209-213.
Jinlong, N., L. Zhongsheng and L. Guangdong, 2000. A study of episodic tectonic evolution in China`s dongying basin. Petrol. Sci., 3: 31-35.
Klein, J.S., P. Mozley, A. Campbell and R. Cole, 1999. Spatial distribution of carbon and oxygen isotopes in laterally extensive carbonate cemented layers: Implication for mode of growth and subsurface identification. J. Sediment. Res., 69: 184-201.
Land, L.S. and S.P. Dutton, 1978. Cementation of Pennsylvanian deltaic sandstone: Isotopic data. J. Sediment Petrol., 48: 1167-1176.
Li, M., G. Taisheng, Z. Xueping, Z. Taijun, G. Rong and D. Zhenrong, 1982. Oil basins and subtle traps in the Eastern part of China, in the deliberate search for the subtle trap. AAPG Memoir., 32: 287-315.
Macaulay, C.I, A.E. Fallic, O.M. McLaughlin, R.S. Haszeldine and M.J. Pearson, 1998. The significance of δ o;C of carbonate cement in reservoir sandstones: A regional perspective from the Jurassic of the Northern North Sea. Special Publ. Int. Sediment., 26: 395-408.
Mccrea, J.M., 1950. On the isotopic chemistry of carbonates and paleotemperature scale. J. Chem. Phys., 18: 849-857.
Milliken, K.L., L.S. Land and R.G. Loucks, 1981. History of burial diagenesis determined from isotopic geochemistry, Frio Formation, Brazoria Country, Texas. Am. Ass. Petrol. Geol. Bull., 65: 1397-1413.
Taylor, K.G., R.L. Gawthorpe, C.D. Curtis, J.D. Marshall and D.N. Awwiller, 2000. Carbonate cementation in a sequence-stratigraphic framework: Upper Cretaceous sandstones, Book Cliffs, Utah-Colorado. J. Sediment. Res., 70: 360-372.
Watson, R.S., N.H. Trewin and A.E. Fallic, 1995. The formation of carbonate cements in the Forth and Balmoral Fields, northern North Sea: A case for biodegradation, carbonate cementation and oil leakage during early burial. Geol. Soc Special Publ., 94: 177-200.
Williams, H., F.J. Turner and C.M. Gilbert, 1982. Petrography: An Introduction to Study of Rock in Thin Section. W.H. Freeman and Co., San Francisco, pp: 325-358.
Zhi, T., 1982. Tectonic features of oil and gas basins in eastern part of China. AAPG Bull., 66: 509-521.