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Articles by Xiao-Ling Wang
Total Records ( 3 ) for Xiao-Ling Wang
  Zong- Wei Li , Pei-Pei Yang , Xiao-Ling Wang and Li-Cun Li
  Two new 1-D manganese(III) Schiff-base complexes bridged by dicyanamide (dca), [Mn(III)(5-Brsalen)(dca)] ⋅ CH3OH (1) and [Mn(III)(3,5-Brsalen)(dca)] · CH3OH · CH3CN (2) (5-Brsalen = N,N′-ethylenebis(5-bromo salicylaldiminato) dianion; 3,5-Brsalen = N,N′-ethylenebis(3,5-dibromosalicylal diminato) dianion), have been synthesized and characterized. X-ray diffraction analyses reveal that the two complexes have 1-D chain structures constructed by μ1,5-dca bridge. Magnetic susceptibility measurements exhibit weak antiferromagnetic exchange coupling in the complexes.
  Xiao-Ling Wang
  A new Fe(II) complex, [Fe(HIM2Py)2(N(CN)2)2] . 2H2O (HIM2py = 1-hydroxyl-2(2′-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1 H-imidazole), has been synthesized and characterized. The X-ray analysis reveals that HIM2py ligands are coordinated to iron as an unusual six-membered bidentate chelate with κ2N(py), O(HIM) mode. The variable-temperature magnetic susceptibility suggests that weak antiferromagnetic interactions exist in the complex.
  Xiao-Ling Wang
  Four radical−Ln(III)−radical complexes, [Ln(hfac)3(NITPhSCH3)2] (Ln = Gd (1), Dy (2), Er (3), Ho (4); hfac = hexafluoroacetylacetonate; NITPhSCH3 = 4’-thiomethylphenyl-4,4,5,5tetramethyl-imidazoline-1-oxyl-3-oxide), have been synthesized, and structurally and magnetically characterized. The X-ray crystal structures show that the structures of the four complexes are similar, consisting of isolated molecules in which Ln(III) ions are coordinated by six oxygen atoms from three hfac and two oxygen atoms from nitronyl radicals. The temperature dependencies of magnetic susceptibilities for the four complexes show that in the Gd(III) complex, ferromagnetic interactions between Gd(III)−radical and antiferromagnetic interactions between the radicals coexist with J Rad−Gd = 1.09 cm−1, J Rad−Rad = −1.85 cm-1.
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