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Articles by Xiang-Gao Meng
Total Records ( 3 ) for Xiang-Gao Meng
  Dan Hu , Lei Chen , Zhi-Quan Pan , Huan Liu , Xiang-Gao Meng and You Song
  A new trinuclear complex, lcub[Cu(L)]33-CO3)rcub(ClO4)4 (L = N-(2-thiophenoethyl)-N,N-bis (3-aminopropyl)amine), was synthesized and characterized by single-crystal X-ray analysis. The complex contained three identical mononuclear copper(II) units connected by the μ3-carbonate formed from atmospheric carbon dioxide. The electronic and magnetic properties were studied by cyclic voltammetry and the measurement of magnetic susceptibility, respectively. The μ3-bridging model revealed weak ferromagnetic coupling of Cu(II), with the J value of -11.28 cm-1 and the Zeeman splitting g value of 2.06, which were determined by means of magnetic measurements in the 2-300 K range.
  Li-Li Wen , Dong-E Wang , Yu-Jin Chen , Xiang-Gao Meng , Dong-Feng Li and She-Ming Lan
  The syntheses, IR, molecular structures, and luminescence of [M(HIMDC)(4, 4`-bipyO)0.5(H2O)]n [H3IMDC = 4, 5-imidazoledicarboxylate, 4, 4`-bipyO = 4, 4`-bipyridine-N, N`-dioxide, M = Co (1) and Zn (2)] are reported. The most notable structure feature of 1 and 2 is that the left-handed and right-handed helical chains constructed from 4,5-imidazoledicarboxylate and metal are linked by 4,4`-bipyO to generate infinite 2-D herringbone architectures. 2 exhibits strong fluorescent emission in the solid state at room temperature.
  Xiang-Hua Wu , Jin-Tao Guan , Guang-Ao Yu , Yu-Hong Yang , Bei Zhang , Xiang-Gao Meng and Sheng-Hua Liu
  {Cu4Br5[(η5-C5H4PPh2)(η5-C5H5)Co]4}[PF6]3, [(η5-C5H4PPh2)(η5-C5H5)Co]+ = ((η5-cyclopentadienyl)[η5-1-(diphenylphosphino) cyclopentadienyl] cobaltocenium) and {Ag(NO3)(CH3COCH3)[(η5-C5H4PPh2)(η5-C5H5)Co]}n[PF6]n have been synthesized and characterized by elemental analyses, infrared spectroscopy, X-ray diffraction techniques, and by cyclic voltammetry. {Cu4Br5[(η5-C5H4PPh2)(η5-C5H5)Co]4}[PF6]3 contains four coplanar copper atoms bridged by four μ-Br and one central μ4-Br occupying the apex of a square pyramid, and {Ag(NO3)(CH3COCH3)[(η5-C5H4PPh2)(η5-C5H5)Co]}n[PF6]n affording a 1-D coordination zigzag polymer.
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