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Tetrahedron
Year: 2009  |  Volume: 65  |  Issue: 29  |  Page No.: 5709 - 5715

Total synthesis of (–)-renieramycin G from L-tyrosine

Xiang Wei Liao, Wei Liu, Wen Fang Dong, Bao He Guan, Shi Zhi Chen and Zhan Zhu Liu    

Abstract: (–)-Renieramycin G was synthesized in 21 steps for the longest linear sequences employing L-tyrosine methyl ester as the chiral starting material in 8.5% overall yield. Two of the four chiral centers came from l-tyrosine methyl ester, and the other two were induced through an intermolecular and an intramolecular Pictet&150;Spengler reaction, respectively.

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