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Journal of Coordination Chemistry
Year: 2011  |  Volume: 64  |  Issue: 22  |  Page No.: 3928 - 3937

A 2-D CdI2 coordination network with 7-oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylate: synthesis, crystal structure, and luminescent properties

Min Hu, Min Chen, Xiao-Gang Yang, Shao-Ming Fang and Chun-Sen Liu    

Abstract: The in situ reaction of Cd(ClO4)2·6H2O with 7-oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylic anhydride in the presence of lithium hydroxide affords a 2-D CdII coordination polymer, [Cd(L)(H2O)] (1) (L = 7-oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylate), which exhibits an unusual (3,6)-connected (46·66·83)(43)2 CdI2-type topology. The luminescent and thermal properties of 1 were investigated.

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