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Journal of Coordination Chemistry
Year: 2011  |  Volume: 64  |  Issue: 21  |  Page No.: 3661 - 3669

A new organic−inorganic hybrid based on Mn−salen and decavanadate

Shiwei Lin, Qiong Wu, Huaqiao Tan and Enbo Wang    

Abstract: An organic−inorganic hybrid based on Mn−salen and decavanadate, [NH4]2[Mn(salen)(H2O)2]4[V10O28] · 6H2O (1) (salen = N,N’-ethylene-bis(salicylideneiminate)), has been synthesized by the strategy of secondary building units in mixed methanol−water solution and was structurally characterized by single-crystal X-ray diffraction, elemental analyses, IR, and UV-Vis. The [Mn(salen)(H2O)2]+ cations and water molecules are located in the interspaces among the polyoxoanions [V10O28]6− forming a POM−based supramolecule. Compound 1 is the first example of metal-Schiff-base polyoxovanadates. The photocatalytic analysis, cyclic voltammetry, and electrocatalytic analysis of 1 have been investigated.

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