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Journal of Coordination Chemistry
Year: 2010  |  Volume: 63  |  Issue: 3  |  Page No.: 418 - 425

A water chain with trimeric/hexameric clusters trapped in a POM/Ln compound

Hai-Jun Pang, Chun-Jing Zhang, Ya-Guang Chen and Dong-Mei Shi    

Abstract: A new 3-D supramolecular compound based on a Keggin polyoxometalate and lanthanide (Ln) coordination cations [Ce(H2O)3L3]2[HSiMo12O40]2[L] ⋅ 7H2O (1) (L = isonicotinic acid) has been synthesized and characterized by routine methods. Compound 1 has a water chain with trimeric and hexameric water clusters trapped in the network. The isonicotinic acid plays a key role in forming the 1-D water chains. Compound 1 shows intense photoluminescence at room temperature.

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