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Journal of Coordination Chemistry
Year: 2009  |  Volume: 62  |  Issue: 17  |  Page No.: 2755 - 2763

Synthesis, structure, and photoluminescence of a series of lanthanide coordination polymers constructed from nitrogen containing organic ligands

Xinxin Xu, Xiaoxia Liu, Ting Sun, Xia Zhang and Enbo Wang    

Abstract: We have synthesized four coordination polymers with two different nitrogen containing organic ligands and different lanthanide metal ions, under hydrothermal condition. [lcubLn2(bpdc)3(H2O)2rcub]n (Ln = Dy (1), Sm (2)) (bpdc = 2,2-bipyridine-3,3-dicarboxylic acid) are isostructural, with 2-D supramolecular layer structure composed from 1-D chains. Like 1 and 2, [lcubLn(pzda)2(H2O)2rcub · 4H2O]n (Ln = Dy (3), Nd (4)) (pzda = pyrazine-2,6-dicarboxylic acid) are also isostructural with 1-D chain-like structures. The photoluminescence of 2 is studied.

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