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Journal of Coordination Chemistry
Year: 2009  |  Volume: 62  |  Issue: 16  |  Page No.: 2675 - 2681

Syntheses, crystal structures, and properties of 2-(1H-tetrazol-1-yl) acetic acid complexes

Degang Ding, Maolin Zhang, Lichao Li, Yaoting Fan and Hongwei Hou    

Abstract: Three new complexes have been prepared based on 2-(1H-tetrazol-1-yl) acetic acid (Htza) and the Ln(III) salts La(NO)3 · 6H2O, PrCl3 · 6H2O, and NdCl3 · 6H2O. Their crystal structures have been characterized by single crystal X-ray crystallography. In each instance, the tetrazole ligand is both bridging and chelating-bridging connecting Ln(III) ions via the oxygens from carboxylate moieties. Thus infinite 1-D coordination polymers are formed. In addition, solid state UV spectra of the complexes are investigated.

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