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Journal of Coordination Chemistry
Year: 2008  |  Volume: 61  |  Issue: 6  |  Page No.: 945 - 955

Synthesis, structures and photoluminescence of two Er(III) coordination polymers

Yu Zhang, Jin Yang, Guo-Dong Li, Feng Zhang and Jie-Sheng Chen    

Abstract: Two new erbium compounds, [Er2(BDC)3(DMF)2] (1) and [Er2(CQC)3(DMF)3(H2O)] · DMF · H2O (2), where BDC stands for 1,4-benzenedicarboxylate, CQC for 2-(4-carboxyquinolin-2-yl)quinoline-4-carboxylate, and DMF for N,N-dimethylformamide, have been synthesized through pre-heating and cooling-down crystallization. In 1 the Er(III) is seven-coordinate with oxygen atoms from six BDC and one DMF, forming a three-dimensional open-framework structure. Compound 2 possesses a 2D structure based on dinuclear Er(III) building units. The photoluminescence of 1 has also been investigated.

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