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Journal of Coordination Chemistry
Year: 2008  |  Volume: 61  |  Issue: 14  |  Page No.: 2266 - 2273

Syntheses, structures and properties of two complexes bridged by [M(CN)2]- (M = Ag (I), Au (I))

Mei-Ling Liu, Li-Zhi Zhang, Xiu-Ping Sun, Zhen-Ping Ma, Wen Gu and Xin Liu    

Abstract: A dinuclear complex Cu2(bpca)2(H2O)2(Ag2(CN)3) (1) and a 1D complex [Cu2(bpca)2(H2O)2(Au(CN)2)2]n (2) (bpca = bis(2-pyridylcarbonyl)amide anion) have been prepared, structurally characterized and 2 has been magnetically characterized. The magnetic properties show an antiferromagnetic interaction between the two Cu(II) ions. Based on the Hamiltonian Hcirc = -2J Σ (Si · Si+1), best fitting for the experimental data leads to J = -0.045 cm-1.

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