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Trends in Applied Sciences Research

Year: 2011 | Volume: 6 | Issue: 8 | Page No.: 910-917
DOI: 10.17311/tasr.2011.910.917
Adsorption Behaviour of Pyrazolo [3, 4-b] Pyridine on Corrosion of Stainless Steel in HCl Solutions
O.O. James, K.O. Ajanaku, K.O. Ogunniran, O.O. Ajani, T.O. Siyanbola and M.O. John

Abstract: The properties of stainless steel makes the alloy suitable for many application; but this tends to change at very aggressive conditions thereby making its properties to fail. The corrosion inhibition efficiency of 2-(4-Methyl-3-oxo-2-phenyl-2, 3-dihydro-1H-pyrazolo [3, 4-b] pyridin-4-yl) acetic acid butylester (PP) on stainless steel in HCl solution was studied by weight loss method. The adsorption mechanism was investigated using adsorption isotherms. The experimental data fit Flory-Huggins and Thermodynamic/El-Awady models. The values for free energy of adsorption, ΔGoads, of PP at different surface coverage, θ, were also calculated by applying the mathematical model of Bockris-Swinkels adsorption isotherm. The variation of free energy of adsorption ΔGoads.with surface coverage, θ, was rationalised in term of interaction between adsorbed PP molecules. A possible adsorption model of PP molecules on to the steel surface was suggested.

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How to cite this article
O.O. James, K.O. Ajanaku, K.O. Ogunniran, O.O. Ajani, T.O. Siyanbola and M.O. John, 2011. Adsorption Behaviour of Pyrazolo [3, 4-b] Pyridine on Corrosion of Stainless Steel in HCl Solutions. Trends in Applied Sciences Research, 6: 910-917.

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