Subscribe Now Subscribe Today
Science Alert
 
Blue
   
Curve Top
Journal of Applied Sciences
  Year: 2002 | Volume: 2 | Issue: 11 | Page No.: 1034-1038
DOI: 10.3923/jas.2002.1034.1038
 
Facebook Twitter Digg Reddit Linkedin StumbleUpon E-mail

Preparation and Chracterization of Zeolite-Based Hydrocracking Catalysts

Shakeel Ahmed , A. Hassan , K. Alam , M. A. Al-Shalabi and T. Inui

Abstract:
A series of zeolite-based hydrocracking catalysts was prepared using modified Y-zeolite and alumina as support. Nickel, tungsten (NiW) and Nickel, Molybdenum (NIMo) metal pairs were used as active metals. The metals were added using incipient wetness impregnation method. Commercial Y-zeolite active was modified by steam treatment at various temperatures and the unit cell size was measured by XRD method. Two sets of catalysts were prepared using modified Y-zeolite and γ-alumina in a ratio of 50:50 and 30:70 respectively. The metal pair loaded on each type of support used was eighter NiMo or NIW. The objective of the study was to investigate the effect of active metal type and the acidity function on the catalytic activity. The prepared catalysts were characterized by surface area, pore volume, Temperature programmed-Desorption (TPD) of ammonia and Temperature Programmed-Reduction (TPR). The hydrocrcking activity was measured using cumene as a model compound. It was observed that NiW- based catalysts were more active in hydrocracking of cumene than were NiMo-based catalysts. The results of TPD of ammonia are not directly correlated with the conversion of cumene, indicating that the Lewis acid sites from γ-alumina are contributing more to the total acidity measure by TPD of ammonia. The hydrocracking activity of the prepared catalysts was also measured using vacuum gas oil as feed in a batch autoclave reactor. All of the prepared catalysts showed good activity in comparison with a commercial hydrocracking catalysts. However, a clear difference in conversion performance could not be obtained under the conditions the catalysts were tested in the batch reactor.
PDF References Citation Report Citation
 RELATED ARTICLES:
  •    Analysis of the Textural Characteristics and Pore Size Distribution of a Commercial Zeolite using Various Adsorption Models
How to cite this article:

Shakeel Ahmed , A. Hassan , K. Alam , M. A. Al-Shalabi and T. Inui , 2002. Preparation and Chracterization of Zeolite-Based Hydrocracking Catalysts. Journal of Applied Sciences, 2: 1034-1038.

DOI: 10.3923/jas.2002.1034.1038

URL: https://scialert.net/abstract/?doi=jas.2002.1034.1038

COMMENT ON THIS PAPER
 
 
 

 

 
 
 
 
 
 
 
 
 

 
 
 
 
 
 
 

Curve Bottom