Statistical Optimization for the Adsorption of Acid Fuchsin onto the Surface of Carbon Alumina Composite Pellet: An Application of Response Surface Methodology
Jayanta Kumar Basu
Industrial effluents mainly enriched with different colored substances cause significant environmental problem. Various efforts have been made so far for the treatment of textile industry effluents but very little attention has been given for the removal of dyes from medicine industry waste water. Acid fuchsin is one of such dyes which are mainly present in the medicine industry waste water. In the present investigation, carbon-alumina composite pellet was developed for the removal of acid fuchsin dye from its aqueous solution. The removal of acid fuchsin was carried through batch adsorption and the effects of different parameters on the adsorption of acid fuchsin were studied through response surface methodology. The composite adsorbent was found to have an adsorption capacity of 181.82 mg g-1 for acid fuchsin. The adsorption process was optimized by using response surface methodology and the effects of various process parameters such as, temperature, solution pH, salt concentration and initial dye concentration on percent dye removal were determined by a four factor Box-Behnken design. The maximum dye removal percentage was obtained for an initial dye concentration of 10 mg L-1 and a solution pH of 7.5 whereas, the temperature is fixed at 35°C. Nevertheless, the maximum removal was found at zero salt concentration. Therefore, it can be concluded that the prepared adsorbent successfully remove acid fuchsin from its aqueous solution. Since the adsorbent is used in the pelletized form, it can be further used in a fixed bed column study.
to cite this article:
Monal Dutta and Jayanta Kumar Basu, 2012. Statistical Optimization for the Adsorption of Acid Fuchsin onto the Surface of Carbon Alumina Composite Pellet: An Application of Response Surface Methodology. Journal of Environmental Science and Technology, 5: 42-53.
May 07, 2011; Accepted: August 19, 2011;
Published: November 02, 2011
In the present decade, huge amount of colored effluent are directly discharge
into water bodies due to rapid growth of industrialization cause significant
environmental problems (Nwude et al., 2011; Nasab
et al., 2010). A huge amount of colored effluents originated from
different dye manufacturing units inevitably lost into water bodies each year
while processing (Arunachalam and Annadurai, 2011; Morais
et al., 1999). These colored substances cause adverse effects on
aquatic life by impeding the rate of photo synthesis (Osman
et al., 2009; Rajendran et al., 2011).
The hematological process of some biota also affects when these colored materials
enter into their systems (Afaq and Rana, 2009; Wanchanthuek
and Thapol, 2011). Various types of toxic dyes such as, acid dyes, basic
dyes, reactive dyes and azo dyes are found in the inland surface water originating
from their different manufacturing sources and users. Among all these dyes,
acid dye is most widely used in pharmaceutical industry has a complex aromatic
structure (Attia et al., 2006). Acid fuchsin
is one of such dyes used as an inhibitor of reverse transpose of immunodeficiency
virus (Baba et al., 1988), as a copper corrosion
inhibitor (Bastidas et al., 2003), in the preparation
of organic inorganic hybrid nano-composite (Bin Hussein
et al., 2004) and as a laboratory reagent. Most of these dyes are
reported to be carcinogenic in nature so often produce toxic amines over incomplete
degradation which in turn necessities the pre-treatment of these colored effluents
prior to disposal (Lata et al., 2007; Vimonses
et al., 2009). The removal of color can be done by coagulation and flocculation
(Amin, 2008; Santhy and Selvapathy,
2006), oxidation (Malik and Saha, 2003), membrane
separation (Ciardelli et al., 2001) and adsorption
(Wu and Tseng, 2008) but adsorption is worth mentioning
amongst all (Dekhil et al., 2011). The activated
carbon is one of the versatile adsorbents because of its large surface area
and highly porous structure, but its high cost limits its widespread use.
Besides, the use of powdered form of adsorbent has the great disadvantage of
separation after being used. To overcome this difficulty, the carbon may be
used in its pelletized form. In addition to carbon, alumina could be used as
a good adsorbent for acid dyes (Gupta and Suhas, 2009;
Adak et al., 2005). Therefore, the use of carbon-alumina
composite pellet could be a better alternative for the removal of an acidic
dye from its aqueous solutions (Balint and Miyazaki, 2009).
The alumina has high mechanical properties and strong resistivity to thermal
degradation (Mahmoud et al., 2004, 2010a).
It also exhibits a high affinity to anionic dyes under basic condition and vice-versa
(Mahmoud et al., 2010b). However, a few studies
have focused on the removal of acidic dyes using polyurethane/chitosan composite
(Zhu et al., 2010), MnFe2O4/bentonite
nano composite (Hashemian, 2010), CuFe2O4-AC
composite (Zhang et al., 2007), Fe2O4-AC
composite (Yang et al., 2008) but no approach
has made for the removal of acid fuchsin using carbon alumina composite pellet.
The adsorption process is influenced by various process parameters such as pH,
initial concentration, temperature etc. and the effects of these parameters
on the adsorption process can be studied through Response Surface Methodology
(RSM) (Lee et al., 2000). Therefore, in the present
investigation a composite adsorbent was developed for the removal of acid fuchsin
by using commercial carbon and alumina where polyvinyl alcohol was used as a
binder. The effects of different process parameters namely, pH, initial concentration,
temperature and salt concentration were studied through response surface methodology.
MATERIALS AND METHODS
Reagents: Commercial granular activated carbon was supplied by SD Fine Chem. Ltd. (Mumbai, India). The alumina powder for the present work was procured from Merck Specialities Pvt. Ltd. (Mumbai, India). Acid fuchsin and Polyvinyl Alcohol (PVA) was purchased from Loba Chemie Pvt. Ltd. (Mumbai, India). All the experiments were carried out at Indian Institute of Technology, Kharagpur, India in the month of June-July, 2011.
Preparation and characterization of the adsorbent: The Activated Carbon (AC), Alumina powder (Al) and PVA as a binder were mixed together in a weight proportion of 2:2:1. Then a small quantity of water was added to the mixture in order to prepare slurry which was then heated up to 80°C for 4 h in a constant temperature water bath. The heating process was carried out till a sticky mass was formed and then the mass was shaped into spherical pellets. The pellets were kept overnight in an air oven at 90°C and placed in tubular furnace where they were heated up to 300°C for 2 h in a flow of nitrogen gas (300 mL min-1). Next the activation was accomplished by continuing the heating for 1 h. The resulting pellets were then cooled down to room temperature and stored in desiccator over silica gel. The prepared pellets were designated as Carbon-alumina Composite (CAC) pellets. The surface properties of the composite materials were analyzed by using BET apparatus (Autosorb-1, Quantachrome, USA).
Adsorption equilibrium: The surface morphology was investigated by using Scanning Electron Microscope (SEM) (Hitachi model SU-70) image and the surface functional groups were determined using Fourier Transform Infrared Spectroscopy (FTIR) (Spectrum-100, Perkinelmer, USA).
Preparation of dye solution: Acid fuchsine dye of commercial purity was used without further purification. The dye stock solution of concentration of 1000 mg L-1 was prepared by dissolving desired quantity of dye in distilled water. The experimental solutions of different initial concentrations were obtained by diluting the dye stock solution.
Equilibrium and kinetic study: Adsorption studies were performed by taking 100 mL of acid fuchsin solutions of varying initial concentration (25-175 mg L-1) in a set of 250 mL conical flasks containing 0.1 g adsorbents. The flasks were agitated in an isothermal mechanical shaker at 35°C for 24 h to reach equilibrium. Whereas, the samples were withdrawn at various interval of time using micro-pipette for kinetic study and centrifuged for 10 min to separate the adsorbent particles. The corresponding concentrations of acid fuchsin were analyzed in a double beam UV-Vis spectrophotometer (Spectra scan UV 2600, Chemito, India). The effect of different parameters like pH, salt concentration, temperature and initial concentration on the percentage of the dye removal was determined by applying box behnken design.
Box behnken design: The response is taken as the percentage removal of dye and was calculated by using the formulae:
where, C0 and Ct are the dye concentrations in mg L-1 at the beginning and at any time t (min), respectively.
Box Behnken Design (BBD): The Box Behnken method was used to determine the interaction between adsorption process parameters and response variable. Temperature (A), pH (B), salt (C) and initial concentration (D), were chosen as the independent input variables and the percent removal of fuchsine acid (Y) was taken as the response or dependent variable. The response variables were correlated to the independent variables by the following polynomial equation:
where, Y is the response and β0, βi, βii
and βij are coefficients of the intercept, linear, square and
interaction effects, respectively. The regression model was statistically analyzed
by using design expert software (Stat-Ease, Inc., version 8.0.4, Minneapolis,
USA). The optimum values of the process parameters were obtained from numerical
optimization. In the BBD the ranges of input variables are provided as per their
higher and lower values and a design matrix is predicted by the software after
performing possible permutations and combinations.
Kinetic study: Once, the experiments are carried out according to the design matrix, different experimental values of output variables are put in the design matrix to determine the optimum experimental conditions. Besides, The adequacy of the models was justified by the Analysis of Variance (ANOVA). It can be predicted from ANOVA that the parameters having probability of F-statistics value less than 0.05 are significant.
RESULTS AND DISCUSSION
Characterization of the prepared CAC pellets: The surface area, total
pore volume and average pore size of CAC pellets were determined by BET surface
area analyzer and the values were found to be 294.1 m2 g-1,
0.2643 cc g-1 and 35.95 D, respectively (Table 1).
The surface morphology of CAC pellets was determined by using SEM image. It
can be seen from Fig. 1 that Al particles are uniformly dispersed
on the surface of CAC. The FTIR spectrum of CAC pellets is shown in Fig.
2. The presence of various surface functional groups such as amine and alkenes
were detected at 1019 and 1020 cm-1 of FTIR spectrum. Besides, the
C-H and O-H bonds were detected at 1422 and 3350 cm-1, respectively
Kinetic study: In order to investigate the controlling mechanism for
acid fuchsin adsorption, pseudo first and second order kinetic model were investigated.
The equation corresponding to the pseudo-first-order kinetic model is expressed
by Eq. 3-4 (Amin, 2009;
Sharma and Goyal, 2010):
|| Results of Bet surface area analysis
|| The SEM image of CAC pellet
|| The FTIR spectra of CAC pellet
|| Adsorption kinetic constant, modeled by a pseudo first-order
|k2 is the equilibrium rate constant for pseudo-first
and second-order kinetics (g mg-1 min-1); qeq,exp
qeq, calc are the experimental and calculated equilibrium adsorption
capacities in mg g-1 for second order kinetics
where, qe and qt refer to the amount of dye adsorbed
(mg g-1) at equilibrium and at any time, t (min), respectively. The
k1 (min-1) and k2 (g mg-1-min) are
the equilibrium rate constant for pseudo-first and second-order kinetics. The
experimental data were fitted well with the second order kinetics. The pseudo
second order model fitted at different dye concentrations (50, 100 and 150 mg
L-1) is shown in Table 2. It is observed that the
adsorption of acid fuchsin increased with increasing initial concentration and
an adsorption capacity of 91 mg g-1 was reached after 120 min for
the initial concentration of 150 mg L-1, whereas, the adsorption
capacity was found to be 39.15 mg g-1 for the initial concentration
of 50 mg L-1 at the same time interval. So, the initial concentration
has the significant effect on the adsorption. The values of the rate constant
(k2) at different acid fuchsin concentration are also shown in Table
2. It is observed that at the lower range of initial concentration the k2-values
increased, whereas, at higher concentration the k2-values became
almost constant. The values of good regression coefficient (R2) were
obtained for each concentration.
The adsorption isotherm: The equilibrium data were fitted to Freundlich,
Langmuir and Tempkin isotherm. The Langmuir isotherm represents the unimolecular
adsorption of the adsorbate molecule on the adsorbent surface (Ozturk
and Kavak, 2005).
The model can be expressed as:
where, KL is the Langmuir constant related to the energy of adsorption
(L mg-1) and qm is the maximum amount of adsorption corresponding
to complete monolayer coverage on the surface (mg g-1). Similarly
the Freundlich isotherm can be used for non-ideal adsorption that involves heterogeneous
surface energy systems (Ergene et al., 2009)
and is expressed by the following equation:
where, KF is a rough indicator of the adsorption capacity and 1/n
is the adsorption intensity. Similarly, Tempkin isotherm describes the heat
of adsorption and interaction between adsorbent-adsorbate molecules (Anbia
et al., 2010). The Tempkin isotherm can be expressed as:
The experimental data fitted with different adsorption isotherm are shown in
Fig. 3. It is observed that the equilibrium behavior was well
described by the Langmuir isotherm model and corresponding monolayer adsorption
capacity was found to be 181.82 mg g-1.
||Fitting of equilibrium models for fuchsin acid (volume-100
mL, rpm-2000, pH-6.01, temperature-303 K)
||The plot between predicted and actual value of percent dye
removal. *Points plotted together factual and predicted values of percent
|| Equilibrium model parameters
The values of parameters obtained for various adsorption isotherms are given
in Table 3. It is observed from the table that a value of
R2 (0.97) in case of Langmuir isotherm is better than other isotherms.
Therefore, conformation of the experimental data into Langmuir isotherm model
indicates the homogeneous nature of CAC surface.
Analysis of variance
Statistical modeling and analysis of variance (ANOVA): A four factor
Box-Behnken design was used to optimize the adsorption process of acid fuchsin.
The design matrix proposed by BBD contained twenty seven experimental runs with
three replicates at the center points. The quadratic model was suggested by
the software for percentage dye removal and the corresponding model equation
is as follows:
The ANOVA of percent removal of acid fuchsin is shown in Table 4. In the present study, A, B, C, D, AD, BD, CD, B2, C2, D2 are significant model terms. The plot between predicted and actual values of percent dye removal is shown in Fig. 4. It showed a well agreement between actual and predicted values of response.
Effects of pH, salt, concentration and temperature on percent removal of acid fuchsin: The combined effect of temperature (A) and pH (B) on percent removal of acid fuchsin (Y) is shown in Fig. 5a. It is observed from Fig. 5a that percent removal of acid fuchsin increased with increase in solution pH and temperature upto 32°C and 64.71% removal was achieved with a solution pH and temperature of 32°C.
|| The analysis of variance of percent dye removal
|Source is the name of term analyzed; df is degree of freedom;
Mean square is sum of square divided by degree of freedom; F-value is the
ratio of mean square for the individual term to the mean square for the
residual. The Prob>F value is the probability of F-statistics value and
is used to test the null hypothesis
Effects of parameters: As the pH of the adsorbate solution increases
the adsorbent surface become more and more basic which in turn enhance the electrostatic
force of attraction between the cationic adsorbent surface and the anionic dye
molecules leads to higher removal percentage (Chun et
al., 2004). The effects of salt concentration (NaCl) (C) and temperature
(A) on percent dye removal is shown in Fig. 5b. It can be
depicted from Fig. 5b the percent removal increased with decrease
in salt concentration and increase in temperature and 66.46% removal was achieved
with a temperature of 32°C and at approximately zero salt concentration.
The effect of ionic strength on percent removal of dye was studied at various
pH ranging from 2-8. Theoretically, electrostatic forces between the adsorbent
surface and adsorbate ions become attractive when the adsorbent surface will
get positively charged. In such a situation, an increase in ionic strength will
decrease the dye removal capacity. Conversely, when the electrostatic attraction
is repulsive, an increase in ionic strength will increase adsorption (Alberghina
et al., 2000). The experimental data from this study followed the
first convention, as the adsorption of positively charged dye molecules on negatively
charged activated carbon decreased with NaCl addition. Consecutively the effects
of solution pH and salt concentration are shown in Fig. 5c.
Here also the percent removal of acid fuchsin was varied in the same way with
pH and salt concentration as discussed earlier. The effect of salt concentration
and solution pH was reconfirmed by Fig. 5c. It is seen from
Fig. 5c that 82.99% acid fuchsin removal can be achieved with
a solution pH of 7.5 and in absence of salt. The combined effects of initial
concentration (D) and temperature (A) are shown in Fig. 5d
and it was noticed that the dye removal capacity increased with decrease in
initial concentration and in increase in temperature. A removal capacity of
51.19% was observed with an initial concentration of 10 mg L-1. As
the concentration of the adsorbate solution increase, large number dye molecules
get adsorbed on the adsorbent surface but, after a certain period of time saturation
reached when no further adsorption takes place. With a high initial dye concentration
the adsorbent surface gets saturated with a very shorter period of time results
into lower dye removal capacity (El-Sayed et al.,
2011). The concentration dependency of dye removal percentage was further
verified by studying the combined effects of concentration and pH (Fig.
||The effects of different parameters on percent dye removal
(a) effects of temperature and pH, (b) effects of salt and temperature,
(c) effects of pH and salt, (d) effects of initial concentration and temperature
and (e) effects of initial concentration and pH
In this case also the maximum removal (84.48%) was obtained at lower initial
concentration (10 mg L-1) and higher solution pH (7.5). Temperature
had a significant effect on the removal of acid fuchsin. The adsorption capacity
of acid fuchsin decreased at higher temperatures which indicates exothermic
nature of the adsorption process. Moreover, the adsorption processes are exothermic
in nature due to release of high amount of heat due to bond formation between
solute and adsorbent (Faust and Aly, 1987).
The carbon alumina composite pellet had shown a good removal capacity for the dye acid fuchsin. With the implementation of this composite adsorbent some of the major drawback of the commercial adsorbents like high cost and low resistivity can be easily overcome. Besides, the presence of alumina in the pellet itself offers high mechanical properties. Many efforts has been made so far to remove various textile dyes form different industrial effluents but very little attention has been given on the removal of acid fuchsin which is largely present in the medicine industry waste.
The present investigation focuses our attention on this particular problem. The adsorption of acid fuchsin is influenced by various adsorption process parameters such as temperature, pH, salt concentration and initial dye concentration and effects of these parameters on the removal percent of acid fuchsin is studied through response surface methodology. The adsorption process is successfully optimized by using a four factor Box-Behnken methodology.
Adak, A., M. Bandyopadhyay and A. Pal, 2005. Removal of crystal violet dye from wastewater by surfactant-modified alumina. Sep. Purif. Technol., 44: 139-144.
Afaq, S. and K.S. Rana, 2009. Toxicological effects of leather dyes on total leukocyte count of fresh water teleost, Cirrhinus mrigala (Ham). Biol. Med., 2: 134-138.
Direct Link |
Al-Jlil, S.A., 2010. Equilibrium study of adsorption of cobalt ions from wastewater using Saudi roasted date pits. Res. J. Environ. Toxicol., 4: 1-12.
CrossRef | Direct Link |
Alberghina, G., R. Bianchini, M. Fichera and S. Fisichella, 2000. Dimerization of cibacron blue F3GA and other dyes: Influence of salts and temperature. Dyes Pigments, 46: 129-137.
Amin, N.K., 2008. Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith. Desalination, 223: 152-161.
Amin, N.K., 2009. Removal of direct blue-106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics. J. Hazard. Mater., 165: 52-62.
Anbia, M., S.A. Hariri and S.N. Ashrafizadeh, 2010. Adsorptive removal of anionic dyes by modified nanoporous silica SBA-3. Applied Surf. Sci., 256: 3228-3233.
Arunachalam, R. and G. Annadurai, 2011. Optimized response surface methodology for adsorption of dyestuff from aqueous solution. J. Environ. Sci. Technol., 4: 65-72.
CrossRef | Direct Link |
Attia, A.A., W.E. Rashwan and S.A. Khedr, 2006. Capacity of activated carbon in the removal of acid dyes subsequent to its thermal treatment. Dyes Pigments, 69: 128-136.
Baba, M., D. Schols, R. Pauwels, J. Balzarini and E. De Clercq, 1988. Fuchsin acid selectively inhibits human immunodeficiency virus (HIV) replication in vitro. Biochem. Biophys. Res. Commun., 155: 1404-1411.
Balint, I. and A. Miyazaki, 2009. Novel preparation method of well-defined mesostructured nanoaluminas via carbon-alumina composites. Micropor. Mesopor. Mater., 122: 216-222.
Bastidas, J.M., P. Pinilla, E. Cano, J.L. Polo and S. Miguel, 2003. Copper corrosion inhibition by triphenylmethane derivatives in sulphuric acid media. Corrosion Sci., 45: 427-449.
Chun, Y., G. Sheng, C.T. Chiou and B. Xing, 2004. Compositions and sorptive properties of crop residue-derived chars. Environ. Sci. Technol., 38: 4649-4655.
Ciardelli, G., L. Corsi and M. Marcucci, 2001. Membrane seperation for watewater reuse in the textile industry. Resour. Conserv. Recycl., 31: 189-197.
Dekhil, A.B., Y. Hannachi, A. Ghorbel and T. Boubaker, 2011. Comparative study of the removal of cadmium from aqueous solution by using low-cost adsorbents. J. Environ. Sci. Technol., 4: 520-533.
CrossRef | Direct Link |
El-Sayed, G.O., T.Y. Mohammed and O.E. El-Sayed, 2011. Removal of basic dyes from aqueous solutions by sugar can stalks. Adv. Applied Sci. Res., 2: 283-290.
Ergene, A., K. Ada, S. Tan and H. Katırcıoglu, 2009. Removal of remazol brilliant blue R dye from aqueous solutions by adsorption onto immobilized Scenedesmus quadricauda: Equilibrium and kinetic modeling studies. Desalination, 249: 1308-1314.
Faust, S. and O. Aly, 1987. Adsorption Processes for Water Treatment. Butterworth Publishers, Boston..
Gupta, V.K. and Suhas, 2009. Application of low-cost adsorbents for dye removal-A review. J. Environ. Manage., 90: 2313-2342.
CrossRef | Direct Link |
Hashemian, S., 2010. MnFe2O4/bentonite nano composite as a novel magnetic material for adsorption of acid red 138. Afr. J. Biotech., 9: 8667-8671.
Direct Link |
Hussein, B.M.Z., A.H. Yahaya, M. Shamsul, H.M. Salleh, T. Yap and J. Kiu, 2004. Acid fuchsin-interleaved Mg-Al-layered double hydroxide for the formation of an organic-inorganic hybrid nanocomposite. Mater. Lett., 58: 329-332.
Lata, H., V.K. Garg and R.K. Gupta, 2007. Removal of a basic dye from aqueous solution by adsorption using Parthenium hysterophorus: An agricultural waste. Dyes Pigments, 74: 653-658.
CrossRef | Direct Link |
Lee, J., L. Ye, W.O. Landen, Jr. and R.R. Eitenmiller, 2000. Optimization of an extraction procedure for the quantification of Vitamin E in tomato and broccoli using response surface methodology. J. Food Comp. Anal., 13: 45-57.
Mahmoud, M.E., M.M. Osman, O.F. Hafez, A.H. Hegazi and E. Elmelegy, 2010. Removal and preconcentration of lead (II) and other heavy metals from water by alumina adsorbents developed by surface-adsorbed-dithizone. Desalination, 251: 123-130.
Mahmoud, M.E., M.S. Masoud and N.N. Maximous, 2004. Synthesis, characterization and selective metal binding properties of physically adsorbed 2-thiouracil on the surface of porous silica and alumina. Microchim. Acta, 147: 111-115.
Mahmoud, M.E., O.F. Hafez, M.M. Osman, A.A. Yakout and A. Alrefaay, 2010. Hybrid inorganic/organic alumina adsorbents-functionalized-purpurogallin for removal and preconcentration of Cr(III), Fe(III), Cu(II), Cd(II) and Pb(II) from underground water. J. Hazard. Mater., 176: 906-912.
Malik, P.K. and S.K. Saha, 2003. Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst Separation. Purificat. Technol., 31: 241-250.
Morais, L.C., O.M. Freitas, E.P. Goncalves, L.T. Vasconcelos and C.G.G. Beca, 1999. Reactive dyes removal from wastewaters by adsorption on eucalyptus bark: Variables that define the process. Water Res., 33: 979-988.
Nasab, S.B., A. Bavi, S. Karami and M. Albaji, 2010. Evaluation of the wastewater-related problems of shoteit river in shushtar (Southwest Iran). Res. J. Environ. Sci., 4: 23-32.
CrossRef | Direct Link |
Nwude, D.O., P.A.C. Okoye and J.O. Babayemi, 2011. Asssesment of heavy metal concentration in the liver of cattle at slaughter during three different seasons. Res. J. Environ. Sci., 5: 288-294.
CrossRef | Direct Link |
Osman, M.M., S.A. El-Fiky, Y.M. Soheir and A.I Abeer, 2009. Impact of water pollution on histopathological and electrophoretic characters of Oreochromis niloticus fish. Res. J. Environ. Toxicol., 3: 9-23.
CrossRef | Direct Link |
Ozturk, N. and D. Kavak, 2005. Adsorption of boron from aqueous solutions using fly ash: Batch and column studies. J. Hazard. Mater., 127: 81-88.
Rajendran, R., S.K. Sundaram and K.U. Maheswari, 2011. Aerobic biodecolorization of mixture of azo dye containing textile effeluent using adapted microbial strains. J. Environ. Sci. Technol., 4: 568-578.
Santhy, K. and P. Selvapathy, 2006. Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon. Bioresour. Technol., 97: 1329-1336.
Sharma, I. and D. Goyal, 2010. Adsorption kinetics: Bioremoval of trivalent chromium from tannery effluent by Aspergillus sp. Biomass. Res. J. Environ. Sci., 4: 1-12.
CrossRef | Direct Link |
Vimonses, V., B. Jina, C.W.K. Chow and C. Saint, 2009. Enhancing removal efficiency of anionic dye by combination and calcination of clay materials and calcium hydroxide. J. Hazard. Mater., 171: 941-947.
Wanchanthuek, R. and A. Thapol, 2011. The kinetic study of methylene blue adsorption over MgO from PVA template preparation. J. Environ. Sci. Technol., 4: 552-559.
CrossRef | Direct Link |
Wu, F.C. and R.L. Tseng, 2008. High adsorption capacity NaOH-activated carbon for dye removal from aqueous solution. J. Hazard. Mater., 152: 1256-1267.
Yang, N., S. Zhu, D. Zhang and S. Xu, 2008. Synthesis and properties of magnetic Fe3O4-activated carbon nanocomposite particles for dye removal. Mater. Lett., 62: 645-647.
Zhang, G., J. Qu, H. Liu, A.T. Cooper and R. Wu, 2007. CuFe2O4/activated carbon composite: A novel magnetic adsorbent for the removal of acid orange II and catalytic regeneration. Chemosphere, 68: 1058-1066.
Zhu, H.Y., R. Jiang and L. Xiao, 2010. Adsorption of an anionic azo dye by chitosan/kaolin/γ-Fe2O3 composites. Applied Clay Sci., 48: 522-526.